Crosslinked capsules of quantum dots by interfacial assembly and ligand crosslinking

被引：115

作者：

Skaff, H ^{[1
]}

Lin, Y ^{[1
]}

Tangirala, R ^{[1
]}

Breitenkamp, K ^{[1
]}

Böker, A ^{[1
]}

Russell, TP ^{[1
]}

Emrick, T ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Polymer Sci & Engn, Conte Ctr Polymer Res, Amherst, MA 01003 USA

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 17期

关键词：

D O I：

10.1002/adma.200500587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Robust crosslinked capsules are produced from water droplets stabilized by oil/water interfacial assembly of norbornene-functionalized CdSe/ZnS core-shell quantum dots that can be crosslinked by ring-opening metathesis polymerization (see Figure). The mechanical integrity of the capsules is maintained after removal of the interface. An amphiphilic polyethylene glycol-substituted ruthenium benzylidene catalyst proved ideal for this interfacial polymerization.

引用

页码：2082 / +

页数：6

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