Cathode electrolysis for the comprehensive recycling of spent lithium-ion batteries

被引：24
作者：
Zhao, Jingjing [1 ]
Qu, Jiakang [1 ]
Qu, Xin [1 ]
Gao, Shuaibo [1 ]
Wang, Dihua [1 ,2 ,3 ]
Yin, Huayi [1 ,2 ,3 ]
机构：
[1] Wuhan Univ, Sch Resource & Environm Sci, Wuhan 430072, Peoples R China
[2] Joint Ctr Green Mfg Energy Storage Mat Wuhan Univ, Wuhan 430072, Peoples R China
[3] Wuhan Univ, Int Cooperat Base Sustainable Utilizat Resources, Wuhan 430072, Peoples R China
来源：
GREEN CHEMISTRY | 2022年 / 24卷 / 16期
关键词：
VALUABLE METALS; SELECTIVE EXTRACTION; RECOVERY; COBALT; LI; SEPARATION; CARBONATE; OXALATE; CO;
D O I：
10.1039/d2gc02118h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Clean lithium-ion battery recycling is indispensable to make the battery market sustainable. Here, we develop an electrochemical approach to separate the cathode film (6 cm x 20 cm) from the Al substrate and simultaneously leach Li and transition metals from the cathode film in 0.5 M H2SO4, leaving behind the conductive carbon and polyvinylidene fluoride binder that are reusable. For LiCoO2 batteries, LiCoO2 was converted to soluble Li+ and Co2+ with a leaching efficiency of over 97%. Besides, the cathode electrolysis is applicable to treat LiMn2O4 and LiNi0.5Co0.2Mn0.3O2. Overall, the cathode electrolysis employs electrons as both reducing agents and exfoliation force, offering a promising pathway to comprehensively reclaim all components from spent cathodes with limited secondary wastes and energy consumption.
引用
收藏
页码：6179 / 6188
页数：10
相关论文
共 49 条
[1]   Recycling End-of-Life Electric Vehicle Lithium-Ion Batteries [J].
Chen, Mengyuan ;
Ma, Xiaotu ;
Chen, Bin ;
Arsenault, Renata ;
Karlson, Peter ;
Simon, Nakia ;
Wang, Yan .
JOULE, 2019, 3 (11) :2622-2646
[2]   Closed Loop Recycling of Electric Vehicle Batteries to Enable Ultrahigh Quality Cathode Powder [J].
Chen, Mengyuan ;
Zheng, Zhangfeng ;
Wang, Qiang ;
Zhang, Yubin ;
Ma, Xiaotu ;
Shen, Chao ;
Xu, Dapeng ;
Liu, Jin ;
Liu, Yangtao ;
Gionet, Paul ;
O'Connor, Ian ;
Pinnell, Leslie ;
Wang, Jun ;
Gratz, Eric ;
Arsenault, Renata ;
Wang, Yan .
SCIENTIFIC REPORTS, 2019, 9 (1)
[3]   Sustainable Recovery of Metals from Spent Lithium-Ion Batteries: A Green Process [J].
Chen, Xiangping ;
Luo, Chuanbao ;
Zhang, Jinxia ;
Kong, Jiangrong ;
Zhou, Tao .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (12) :3104-3113
[4]   Examining different recycling processes for lithium-ion batteries [J].
Ciez, Rebecca E. ;
Whitacre, J. F. .
NATURE SUSTAINABILITY, 2019, 2 (02) :148-156
[5]  
Dai Q., 2019, Argonne National Laboratory, DOI 10.2172/1530874
[6]   A General Method for Regenerating Catalytic Electrodes [J].
Dong, Qi ;
Li, Tangyuan ;
Yao, Yonggang ;
Wang, Xizheng ;
He, Shuaiming ;
Li, Jingyi ;
Luo, Jingru ;
Zhang, Haochuan ;
Pei, Yong ;
Zheng, Chaolun ;
Hong, Min ;
Qiao, Haiyu ;
Gao, Jinlong ;
Wang, Dunwei ;
Yang, Bao ;
Hu, Liangbing .
JOULE, 2020, 4 (11) :2374-2386
[7]   Simultaneous optical detection and extraction of cobalt(II) from lithium ion batteries using nanocollector monoliths [J].
El-Safty, Sherif A. ;
Awual, Md. R. ;
Shenashen, M. A. ;
Shahat, A. .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 176 :1015-1025
[8]   Selective Recovery of Silver(I) Ions from E-Waste using Cubically Multithiolated Cage Mesoporous Monoliths [J].
Elshehy, Emad A. ;
Shenashen, Mohamed A. ;
El-Magied, Mahmoud O. Abd ;
Tolan, Dina A. ;
El-Nahas, Ahmed M. ;
Halada, Kohmei ;
Atia, Asem A. ;
El-Safty, Sherif A. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (41) :4823-4833
[9]   Low-Temperature Molten-Salt-Assisted Recovery of Valuable Metals from Spent Lithium-Ion Batteries [J].
Fan, Ersha ;
Li, Li ;
Lin, Jiao ;
Wu, Jiawei ;
Yang, Jingbo ;
Wu, Feng ;
Chen, Renjie .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (19) :16144-16150
[10]   Progress in the sustainable recycling of spent lithium-ion batteries [J].
Fan, Min ;
Chang, Xin ;
Meng, Qinghai ;
Wan, Li-Jun ;
Guo, Yu-Guo .
SUSMAT, 2021, 1 (02) :241-254
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