Synthesis and Characterization of a Series of Nickel Complexes with Tripodal and Related Ligands: Electroreductive Coupling of Alkynes and Carbon Dioxide

被引：7

作者：

Alexopoulou, Konstantina I. ^{[1
]}

Leibold, Michael ^{[2
]}

Walter, Olaf ^{[3
]}

Zevaco, Thomas A. ^{[4
]}

Schindler, Siegfried ^{[1
]}

机构：

[1] Justus Liebig Univ Giessen, Inst Anorgan & Analyt Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany

[2] Univ Kassel Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany

[3] European Commiss, DG Joint ResearchCtr, Directorate Nucl Safety & Secur G, GI Adv Nucl Knowledge 5, POB 2340, D-76125 Karlsruhe, Germany

[4] Inst Katalyseforsch & Technol Bau 727, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 40期

关键词：

Nickel; Carbon dioxide; Butadiene; Alkynes; Tripodal ligands; COPPER(II) COMPLEXES; MAGNETIC-PROPERTIES; CO2; RELEVANCE; CATALYSIS; DINUCLEAR; IRON(II); CRYSTAL; ADDUCTS; COBALT;

D O I：

10.1002/ejic.201700854

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nickel(II) complexes of a series of tripodal ligands (and derivatives), for example, [Ni(Me(6)tren)(DMF)](ClO4)(2) [Me(6)tren = tris(2-dimethylaminoethyl)-amine], are prepared and structurally characterized. The complexes are tested for their potential to be used as mediators for electroreductive coupling of butadiene and carbon dioxide. From the whole series, the complex [Ni(Me(5)dien)(DMF)(3)](ClO4)(2) (Me(5)dien = 1,1,4,7,7-pentamethyl-diethylenetriamine) yields the highest amount of 3 hexene-1,6 diacid (HDS), thus leading to the same result as the best nickel complex (with the ligand 2,4,4-trimethyl-1,5,9-triazacyclodecan, N3) so far reported in the literature.

引用

页码：4722 / 4732

页数：11

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