Radical addition to "Cation pool". Reverse process of radical cation fragmentation

被引:58
|
作者
Maruyama, T [1 ]
Suga, S [1 ]
Yoshida, JI [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Synth Chem & Biol Chem, Kyoto 6158510, Japan
关键词
D O I
10.1021/ja0511218
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested. Copyright © 2005 American Chemical Society.
引用
收藏
页码:7324 / 7325
页数:2
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