Architecture engineering of carbonaceous anodes for high-rate potassium-ion batteries

被引:48
作者
Wu, Tianlai [1 ,2 ]
Zhang, Weicai [1 ,2 ]
Yang, Jiaying [3 ,4 ]
Lu, Qiongqiong [5 ]
Peng, Jing [1 ,2 ]
Zheng, Mingtao [1 ,2 ]
Xu, Fei [3 ,4 ]
Liu, Yingliang [1 ,2 ]
Liang, Yeru [1 ,2 ]
机构
[1] South China Agr Univ, Coll Mat & Energy, Guangdong Prov Engn Technol Res Ctr Opt Agr, Key Lab Biobased Mat & Energy,Minist Educ, 483 Wushan Rd, Guangzhou 510642, Peoples R China
[2] Guangdong Lab Lingnan Modern Agr, Guangzhou, Peoples R China
[3] Northwestern Polytech Univ, Sch Mat Sci & Engn, Ctr Nano Energy Mat, State Key Lab Solidicat Proc, Xian 710072, Peoples R China
[4] Shaanxi Joint Lab Graphene NPU, Xian 710072, Peoples R China
[5] Leibniz Inst Solid State & Mat Res IFW Dresden, Dresden, Germany
基金
中国国家自然科学基金;
关键词
carbonaceous anodes; electronic conductivity; high-rate performance; ion diffusivity; potassium-ion batteries; METAL-ORGANIC FRAMEWORKS; DOPED HOLLOW CARBON; BINDER-FREE ANODE; K-ION; POROUS CARBON; CYCLE LIFE; SCALABLE SYNTHESIS; UNIVERSAL ANODE; RATE CAPABILITY; HIGH-CAPACITY;
D O I
10.1002/cey2.99
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The limited lithium resource in earth's crust has stimulated the pursuit of alternative energy storage technologies to lithium-ion battery. Potassium-ion batteries (KIBs) are regarded as a kind of promising candidate for large-scale energy storage owing to the high abundance and low cost of potassium resources. Nevertheless, further development and wide application of KIBs are still challenged by several obstacles, one of which is their fast capacity deterioration at high rates. A considerable amount of effort has recently been devoted to address this problem by developing advanced carbonaceous anode materials with diverse structures and morphologies. This review presents and highlights how the architecture engineering of carbonaceous anode materials gives rise to high-rate performances for KIBs, and also the beneficial conceptions are consciously extracted from the recent progress. Particularly, basic insights into the recent engineering strategies, structural innovation, and the related advances of carbonaceous anodes for high-rate KIBs are under specific concerns. Based on the achievements attained so far, a perspective on the foregoing, and proposed possible directions, and avenues for designing high-rate anodes, are presented finally.
引用
收藏
页码:554 / 581
页数:28
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