[(6-Methyl-2-pyridylmethyl)(2-pyridylmethyl)amine][(2-pyridylmethyl)amine]copper(II) bis(perchlorate)

被引：1
作者：
Butcher, Ray J. [1 ]
Tesema, Yohannes T. [1 ]
Yisgedu, Teshome B. [1 ]
Gultneh, Yilma [1 ]
机构：
[1] Howard Univ, Dept Chem, Washington, DC 20059 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536807062952
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu(C6H8N2)(C13H15N3)](ClO4)(2), is a mixed ligand complex with the Cu-II atom coordinated by (6-methyl-2-pyridylmethyl)(2-pyridylmethyl) amine, acting as a tridentate ligand, and 2-(2-aminomethyl) pyridine, as a bidentate ligand, leading to an N-5 square-pyramidal geometry. The amine H atoms are involved in hydrogen bonding to the perchlorate O atoms and there are extensive but weak intermolecular C-H center dot center dot center dot O interactions in the crystal structure. The perchlorate ions are each disordered over two positions, with site occupancies of 0.601 (8):0.399 (8) and 0.659 (11):0.341 (11).
引用
收藏
页码：M74 / U732
页数：14
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