[(6-Methyl-2-pyridylmethyl)(2-pyridylmethyl)amine][(2-pyridylmethyl)amine]copper(II) bis(perchlorate)

被引:1
|
作者
Butcher, Ray J. [1 ]
Tesema, Yohannes T. [1 ]
Yisgedu, Teshome B. [1 ]
Gultneh, Yilma [1 ]
机构
[1] Howard Univ, Dept Chem, Washington, DC 20059 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词
D O I
10.1107/S1600536807062952
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu(C6H8N2)(C13H15N3)](ClO4)(2), is a mixed ligand complex with the Cu-II atom coordinated by (6-methyl-2-pyridylmethyl)(2-pyridylmethyl) amine, acting as a tridentate ligand, and 2-(2-aminomethyl) pyridine, as a bidentate ligand, leading to an N-5 square-pyramidal geometry. The amine H atoms are involved in hydrogen bonding to the perchlorate O atoms and there are extensive but weak intermolecular C-H center dot center dot center dot O interactions in the crystal structure. The perchlorate ions are each disordered over two positions, with site occupancies of 0.601 (8):0.399 (8) and 0.659 (11):0.341 (11).
引用
收藏
页码:M74 / U732
页数:14
相关论文
共 50 条
  • [1] Structures of Mn(II) complexes of bis(2 pyridylmethyl)amine (bpa) and (2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amine (Mebpa): geometric isomerism in the solid state
    Gultneh, Yilma
    Ahvazi, Bijan
    Tesema, Yohannes T.
    Yisgedu, Teshome B.
    Butcher, Ray J.
    JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (16) : 1835 - 1846
  • [2] [Bis(2-pyridylmethyl)amine]dichloridomercury(II)
    Kim, Young-Inn
    Lee, You-Soon
    Seo, Hoe-Joo
    Nam, Ki-Sun
    Kang, Sung Kwon
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M358 - U762
  • [3] (Acetonitrile)[bis(2-pyridylmethyl)-amine]bis(perchlorato)copper(II)
    Butcher, Ray J.
    Tesema, Yohannes T.
    Yisgedu, Teshome B.
    Gultneh, Yilma
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M233 - U2221
  • [4] DIAZOTIZATION OF 2-PYRIDYLMETHYL AMINE
    BOYER, JH
    WOLFORD, LT
    JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (07): : 1053 - 1054
  • [5] Bis(2-pyridylmethyl)amine-borane
    Ballester, NS
    Fontecha, JB
    Wikaira, J
    McKee, V
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O567 - O568
  • [6] (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate
    Li, Hong
    Zhao, Hong Yan
    Zhang, Shi Guo
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M495 - U586
  • [7] [Benzyl(2-pyridylmethyl)amine]dichloridomercury(II)
    Seo, Hoe-Joo
    Kim, Young-Inn
    Lee, You-Soon
    Kang, Sung Kwon
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M55 - U626
  • [8] (2-Pyridylmethyl)ammonium pyridine-2-carboxylate: the product of oxidative degradation of bis(2-pyridylmethyl)amine
    Dossing, A
    Skands, MC
    Madsen, AO
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 (12): : 1460 - 1461
  • [9] Bis(2-pyridylmethyl)ammonium perchlorate
    Butcher, RJ
    Gultneh, Y
    Khan, AR
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : o858 - o859
  • [10] Synthesis and structural characterisation of cobalt(II) and iron(II) chloride complexes containing bis(2-pyridylmethyl)amine and tris(2-pyridylmethyl)amine ligands
    Davies, CJ
    Solan, GA
    Fawcett, J
    POLYHEDRON, 2004, 23 (18) : 3105 - 3114