Heteroleptic copper(II) complexes with 2-bromo-5-methylpyridine: Structures, features of non-covalent interactions and magnetic behavior

被引：9
作者：
Adonin, Sergey A. [1 ,2 ,3 ,4 ]
Novikov, Alexander S. [5 ]
Chernova, Katerina, V [3 ]
Vinnik, Denis A. [4 ]
Taskaev, Sergey, V [4 ]
Korolkov, Ilya, V [1 ,2 ]
Ilyina, Ekaterina, V [6 ]
Pavlov, Alexander A. [7 ]
Novikov, Valentin V. [7 ]
Sokolo, Maxim N. [1 ,2 ,8 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentieva St 3, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Pirogova St 2, Novosibirsk 630090, Russia
[3] Tyumen Ind Univ, Tobolsk Ind Inst, Zona Vuzov 5, Tobolsk 626158, Russia
[4] South Ural State Univ, Chelyabinsk 454080, Russia
[5] St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg 199034, Russia
[6] Boreskov Inst Catalysis SB RAS, Lavrentieva St 5, Novosibirsk 630090, Russia
[7] Nesmeyanov Inst Organoelement Cpds RAS, Vavilova St 28, Moscow 119334, Russia
[8] Kazan Fed Univ, Alexander Butlerov Inst Chem, Lobachevskogo Str 1-29, Kazan 420008, Russia
来源：
INORGANICA CHIMICA ACTA | 2020年 / 502卷
基金：
俄罗斯科学基金会;
关键词：
Copper; N-donor ligands; Magnetic properties; Supramolecular contacts; HALOGEN BOND; M-X; CL; DONOR; RADII; VAN; BR;
D O I：
10.1016/j.ica.2019.119333
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Isostructural complexes [Cu(2-Br-5-MePy)(2)X-2] (2-Br-5-MePy = 2-bromo-5-methylpyridine, X = Cl (1), Br (2) were prepared and structurally characterized. Magnetic measurements reveal that both complexes demonstrate paramagnetic behavior.
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页数：4
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