Photoinduced Controlled Radical Polymerization

被引：227

作者：

Tasdelen, Mehmet Atilla ^{[1
]}

Uygun, Mustafa ^{[1
]}

Yagci, Yusuf ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, Fac Sci & Letters, TR-34469 Istanbul, Turkey

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2011年 / 32卷 / 01期

关键词：

atom transfer radical polymerization (ATRP); living polymerization; metal-organic catalysts/organometallic catalysts; photochemistry; photopolymerization; METHYL ACRYLATE; ACID COMPLEXES; COPPER; PHOTOPOLYMERIZATION; PHOTOINIFERTERS; POLYMERS; KINETICS; STYRENE; AGENT;

D O I：

10.1002/marc.201000351

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Well-controlled radical polymerization of methyl methacrylate can be achieved by in situ photochemical generation of copper (I) complex from air-stable copper (II) species without using any reducing agent at room temperature. The living character of this polymerization was confirmed by both the linear tendency of molecular weight evolution with conversion and a chain extension experiment.

引用

页码：58 / 62

页数：5

共 30 条

[1] Controlled/living radical polymerization: Features, developments, and perspectives [J].

Braunecker, Wade A. ;

Matyjaszewski, Krzysztof .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :93-146

[2] MARK-HOUWINK-SAKURADA COEFFICIENTS FOR CONVENTIONAL POLY(METHYL METHACRYLATE) IN TETRAHYDROFURAN [J].

CHEN, YJ ;

LI, JB ;

HADJICHRISTIDIS, N ;

MAYS, JW .

POLYMER BULLETIN, 1993, 30 (05) :575-578

[3] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[4] PHOTOREDOX CHEMISTRY OF CHLORO AND BROMO COMPLEXES OF COPPER(II) IN METHANOLIC MEDIUM [J].

DAVID, PG ;

DASILVA, PAC .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (12) :3566-3569

[5] Photoinitiated crosslinking polymerisation [J].

Decker, C .

PROGRESS IN POLYMER SCIENCE, 1996, 21 (04) :593-650

[6]

DOI T, 1994, J POLYM SCI POL CHEM, V32, P2911, DOI 10.1002/pola.1994.080321512

[7] Photochemical mechanism of the formation of nanometer-sized copper by UV irradiation of ethanol bis(2,4-pentandionato)copper(II) solutions [J].

Giuffrida, S ;

Condorelli, GG ;

Costanzo, LL ;

Fragalà, IL ;

Ventimiglia, G ;

Vecchio, G .

CHEMISTRY OF MATERIALS, 2004, 16 (07) :1260-1266

[8] A remarkable visible light effect on atom-transfer radical polymerization [J].

Guan, ZB ;

Smart, B .

MACROMOLECULES, 2000, 33 (18) :6904-6906

[9] Toward Nitroxide-Medlated Photopolymerization [J].

Guillaneuf, Yohann ;

Bertin, Denis ;

Gigmes, Didier ;

Versace, Davy-Louis ;

Lalevee, Jacques ;

Fouassier, Jean-Pierre .

MACROMOLECULES, 2010, 43 (05) :2204-2212

[10] New polymer synthesis by nitroxide mediated living radical polymerizations [J].

Hawker, CJ ;

Bosman, AW ;

Harth, E .

CHEMICAL REVIEWS, 2001, 101 (12) :3661-3688

← 1 2 3 →