The Electrochemical Behavior of a Nanocomposite Based on Polyaniline and Thermally Expanded Graphite on Graphite Foil in a Lithium Aprotic Electrolyte

被引：0
|
作者：
Tkachenko, L., I [1 ]
Nikolaeva, G., V [1 ]
Efimov, O. N. [1 ]
Dremova, N. N. [1 ]
Ionov, S. G. [2 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
来源：
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES | 2021年 / 57卷 / 04期
关键词：
nanocomposite; polyaniline; thermally expanded graphite; film coatings; lithium aprotic electrolyte; graphite foil; SURFACE-AREA; CARBON; SUPERCAPACITORS; OXIDE; FABRICATION; COMPOSITES;
D O I：
10.1134/S2070205121040237
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
A synthesis method has been developed, and the electrochemical properties of a nanocomposite coating based on polyaniline (Pani) and thermally expanded graphite (TEG) on a substrate of anodized graphite foil in an aprotic lithium electrolyte have been studied. Stable suspensions of Pani-TEG were obtained by mixing a solution of Pani base in formic acid with TEG and subsequent ultrasonic treatment and deposited on the porous surface of activated (anodized) graphite foil. The specific electrochemical capacity of the coating attained 675 F/g at a charge-discharge current of 0.5 mA/cm(2) in an aprotic electrolyte of 1 M LiClO4 in propylene carbonate. Upon long cycling for a week (more than 300 cycles), the drop in capacity was not higher than 4%.
引用
收藏
页码：713 / 722
页数：10
相关论文
共 50 条
  • [31] Electrochemical Synthesis of Coatings Based on Polydiphenylamine-2-carboxylic Acid on Anodized Graphite Foil Modified by Graphene Nanosheets and Manganese Oxides
    Abalyaeva, V. V.
    Dremova, N. N.
    Baskakova, Yu. V.
    Kabachkov, E. N.
    Baskakov, S. A.
    Efimov, O. N.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2022, 58 (05) : 398 - 410
  • [32] On the electrochemical performance of anthracite-based graphite materials as anodes in lithium-ion batteries
    Camean, Ignacio
    Lavela, Pedro
    Tirado, Jose L.
    Garcia, A. B.
    FUEL, 2010, 89 (05) : 986 - 991
  • [33] A novel electrochemical sensor based on MnOOH nanorod/expanded graphite for sensitive monitoring of metronidazole
    Hu, Xiaomin
    Zhang, Yuanyuan
    Zeng, Ting
    Wan, Qijin
    Wu, Kangbing
    Yang, Nianjun
    DIAMOND AND RELATED MATERIALS, 2022, 128
  • [34] A versatile sensing platform based on FeOOH nanorod/expanded graphite for electrochemical quantification of bioanalytes
    Meng, Kewei
    Hu, Xiaomin
    Zhang, Yuanyuan
    Zeng, Ting
    Wan, Qijin
    Lai, Guosong
    Chen, Xinyue
    Yang, Nianjun
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2021, 902
  • [35] Effects of preparation temperature of graphite oxide on the structure of graphite and electrochemical properties of graphene-based lithium-ion batteries
    Huang Le-Xu
    Chen Yuan-Fu
    Li Ping-Jian
    Huan Ran
    He Jia-Rui
    Wang Ze-Gao
    Hao Xin
    Liu Jing-Bo
    Zhang Wan-Li
    Li Yan-Rong
    ACTA PHYSICA SINICA, 2012, 61 (15)
  • [36] Application of expanded graphite-based materials for rechargeable batteries beyond lithium-ions
    Li, Le
    Zhang, Weizhuo
    Pan, Weijie
    Wang, Mengyu
    Zhang, Hairan
    Zhang, Duo
    Zhang, Dan
    NANOSCALE, 2021, 13 (46) : 19291 - 19305
  • [37] Electrochemical Capacitance Properties of Electrode Based on Polyaniline Coated Graphite Nanoplatelets/Polystyrene Composite Film
    Zia, Tanveer Ul Haq
    Khan, Ahmad Nawaz
    Ara, Behisht
    Gul, Kashif
    JOURNAL OF ELECTROCHEMICAL ENERGY CONVERSION AND STORAGE, 2020, 17 (01)
  • [38] Detection of cadmium (II) ion in water by a novel electrochemical sensor based on modification of graphite carbon nitride and polyaniline composite
    Wang, Xiaolei
    Wang, Rong
    Xue, Qiang
    Liu, Zeyu
    Liu, Yao
    Wang, Jingxia
    Zhu, Changchun
    DIAMOND AND RELATED MATERIALS, 2023, 140
  • [39] Nano-Sn embedded in expanded graphite as anode for lithium ion batteries with improved low temperature electrochemical performance
    Yan, Yong
    Ben, Liubin
    Zhan, Yuanjie
    Huang, Xuejie
    ELECTROCHIMICA ACTA, 2016, 187 : 186 - 192
  • [40] FEW-LAYER GRAPHENE PARTICLES BASED ON THERMALLY EXPANDED COINTERCALATE OF GRAPHITE NITRATE WITH ACETIC AND FORMIC ACIDS
    Davydova, A. A.
    Raksha, E., V
    Oskolkova, O. N.
    Gnatovskaya, V. V.
    Sukhov, P., V
    Padun, O. M.
    Glazunova, V. A.
    Burkhovetskij, V. V.
    Volkova, G. K.
    Berestneva, Yu, V
    Savoskin, M., V
    PHYSICAL AND CHEMICAL ASPECTS OF THE STUDY OF CLUSTERS NANOSTRUCTURES AND NANOMATERIALS, 2020, (12) : 580 - 590
12345