Two-dimensional silver(I) coordination polymer with twisted naphthalene rings

被引：14

作者：

Suenaga, Y ^{[1
]}

Konaka, H

Kitamura, K

Kuroda-Sowa, T

Maekawa, M

Munakata, M

机构：

[1] Kinki Univ, Dept Chem, Osaka 5778502, Japan

[2] Kinki Univ, Sci & Technol Res Inst, Osaka 5778502, Japan

来源：

INORGANICA CHIMICA ACTA | 2003年 / 351卷

关键词：

silver(I) complex; octakis(cyclohexylsulfanyl)naphthalene; two-dimensional sheet structure; twisted naphthalene ring;

D O I：

10.1016/S0020-1693(03)00190-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The silver(I) complex of octakis(cyclohexylsulfanyl)-naphthalene (ochsn), [Ag-4(ochsn)(CF3COO)(4)](CH2Cl2) (1), has been prepared and its molecular structure was determined by X-ray crystallography. In 1, the silver ion prefers a tetrahedral coordination geometry comprised of two S atoms from the ochsn molecules and the two O atoms from the counter anion then producing two-dimensional sheet structure. Interestingly, the naphthalene ring in the complex has large deviations from planarity and end-to-end twists on the order of 35degrees. In contrast, the central naphthalene ring of ochsn shows almost a planar structure in the solid state. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：379 / 384

页数：6