Heteroatom doped porous carbon derived from hair as an anode with high performance for lithium ion batteries

被引:53
作者
Ou, Junke [1 ]
Zhang, Yongzhi [2 ]
Chen, Li [3 ]
Yuan, Hongyan [3 ]
Xiao, Dan [1 ,2 ,3 ]
机构
[1] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610065, Peoples R China
[3] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
关键词
LI STORAGE PROPERTIES; ELECTRODE MATERIALS; MESOPOROUS CARBON; GRAPHENE; INSERTION; CAPACITY; SULFUR; BIOMASS; ACTIVATION; STRAW;
D O I
10.1039/c4ra12121j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heteroatom doped porous carbon (HDPC) is fabricated using human hair as a carbon source via an acid pretreatment procedure and subsequent KOH activation. With the introduction of acid pretreatment, the obtained HDPC possesses a large specific surface area and an appropriate heteroatom doping level. As an anode material for lithium ion batteries, the as-synthesized HDPC delivers a superior specific capacity of 1331 mA h g(-1) at 0.1 A g(-1) and shows an impressive rate capability of 470 mA h g(-1) at 5 A g(-1). Even at an ultrahigh current density of 10 A g(-1), the reversible capacity is still as high as 205 mA h g(-1). The excellent electrochemical performance of HDPC could be ascribed to the high specific surface area, well-formed micro- and mesoporosity and heteroatom doping effects.
引用
收藏
页码:63784 / 63791
页数:8
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