Prototypical arsine-triel adducts (R3AsEX3 for E = B, Al, and Ga)

被引：8
作者：
Conrad, Eamonn [1 ]
Pickup, Janet [1 ]
Burford, Neil [1 ]
McDonald, Robert [2 ]
Ferguson, Michael J. [2 ]
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
[2] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2010年 / 88卷 / 08期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
arsine-triel; (boron; aluminum; gallium) Lewis adducts; CRYSTAL-STRUCTURES; COMPLEXES; BONDS; COORDINATION; ALUMINUM; HALIDES; CATIONS;
D O I：
10.1139/V10-029
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Complexes of arsine ligands (R3As, R = Me, Et, Ph) and Lewis acids of group-13 elements of the form EX3 (E = B, X = Ph, C6F5; E = Al, X = Cl, Br, I; E = Ga, X = Cl) have been isolated and characterized by X-ray crystallography, infrared spectroscopy, H-1, C-13{1H}, B-11{1H}, and Al-27 NMR spectroscopy. The compounds are compared with rare arsine-triel adducts.
引用
收藏
页码：797 / 803
页数：7
相关论文
共 21 条
  • [11] JOHANSEN JD, 1992, ADV MATER OPT ELECTR, V1, P29
  • [12] Synthesis and characterization of single-source precursors to nanocrystalline GaP, GaPxAs1-x, and GaPxSb1-x.: X-ray crystal structures of [Et2GaP(SiMe3)2]2, (Me3Si)2P[μ-GaEt2]2As(SiMe3)2, and (Me3Si)2P[μ-GaEt2]2Sb(SiMe3)2
    Jouet, RJ
    Wells, RL
    Rheingold, AL
    Incarvito, CD
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 601 (01) : 191 - 198
  • [13] Kilah NL, 2008, DALTON T, P2480, DOI 10.1039/b800965a
  • [14] Experimental and computational studies of R3Al-ER′3 (E = P, As, Sb, Bi; R = Et, t-bu; R′ = SiMe3, i-Pr) donor-acceptor complexes:: Role of the central pnictine and the substituents on the structure and stability of alane adducts
    Kuczkowski, A
    Schulz, S
    Nieger, M
    Schreiner, PR
    [J]. ORGANOMETALLICS, 2002, 21 (07) : 1408 - 1419
  • [15] SYNTHESES, STRUCTURES, AND SPECTROSCOPIC STUDIES OF SEVERAL NEW CLASSES OF COMPOUNDS HAVING BORON ARSENIC BONDS
    PETRIE, MA
    OLMSTEAD, MM
    HOPE, H
    BARTLETT, RA
    POWER, PP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (08) : 3221 - 3226
  • [16] A donor-stabilization strategy for the preparation of compounds featuring P=B and As=B double bonds
    Rivard, Eric
    Merrill, W. Alexander
    Fettinger, James C.
    Power, Philip P.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (36) : 3800 - 3802
  • [17] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [18] Reactions of phosphines with electron deficient boranes
    Welch, Gregory C.
    Prieto, Roberto
    Dureen, Meghan A.
    Lough, Alan J.
    Labeodan, Oijsamola A.
    Hoeltrichter-Roessmann, Thorsten
    Stephan, Douglas W.
    [J]. DALTON TRANSACTIONS, 2009, (09) : 1559 - 1570
  • [19] SYNTHESIS AND CHARACTERIZATION OF NOVEL ALUMINUM ARSENIC COMPOUNDS - CRYSTAL-STRUCTURE OF [ET2ALAS(SIME3)2]2
    WELLS, RL
    MCPHAIL, AT
    SPEER, TM
    [J]. ORGANOMETALLICS, 1992, 11 (02) : 960 - 963
  • [20] REACTION OF LIE(SIME3)2 WITH COMPOUNDS CONTAINING 4-MEMBERED CORES OF THE GENERAL FORMULA MEM(CL) (M = IN, E = AS, P, M = GA, E = AS) - NOVEL REARRANGEMENT REACTIONS TO FORM THE ADDUCTS R3M-BULLET-AS(SIME3)3 (R = ME3SICH2, M = IN, R = PH, M = GA)
    WELLS, RL
    MCPHAIL, AT
    JONES, LJ
    SELF, MF
    BUTCHER, RJ
    [J]. ORGANOMETALLICS, 1992, 11 (07) : 2694 - 2697
123