Prototypical arsine-triel adducts (R3AsEX3 for E = B, Al, and Ga)

被引：8
作者：
Conrad, Eamonn [1 ]
Pickup, Janet [1 ]
Burford, Neil [1 ]
McDonald, Robert [2 ]
Ferguson, Michael J. [2 ]
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
[2] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada
来源：
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2010年 / 88卷 / 08期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
arsine-triel; (boron; aluminum; gallium) Lewis adducts; CRYSTAL-STRUCTURES; COMPLEXES; BONDS; COORDINATION; ALUMINUM; HALIDES; CATIONS;
D O I：
10.1139/V10-029
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Complexes of arsine ligands (R3As, R = Me, Et, Ph) and Lewis acids of group-13 elements of the form EX3 (E = B, X = Ph, C6F5; E = Al, X = Cl, Br, I; E = Ga, X = Cl) have been isolated and characterized by X-ray crystallography, infrared spectroscopy, H-1, C-13{1H}, B-11{1H}, and Al-27 NMR spectroscopy. The compounds are compared with rare arsine-triel adducts.
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收藏
页码：797 / 803
页数：7
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