Titanium(IV) complexes of trianionic amine triphenolate ligands

被引：93

作者：

Kol, M ^{[1
]}

Shamis, M

Goldberg, I

Goldschmidt, Z

Alfi, S

Hayut-Salant, E

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel

[3] Coll Judea & Samaria, IL-44837 Ariel, Israel

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 04期

基金：

以色列科学基金会;

关键词：

phenolate ligands; tripodal ligands; titanium complexes; X-ray structure;

D O I：

10.1016/S1387-7003(01)00157-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two trianionic amine triphenolate ligands are introduced and their isopropoxide Ti(IV) complexes synthesized. The two complexes are mononuclear and C-3-symmetrical on the NMR timescale. High barriers to inversion (DeltaG double dagger > 65 KJ mol(-1)) between the enantiomers of each complex were found. The complex derived from the bulkier tripodal ligand shows a better resistance to hydrolysis. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：177 / 179

页数：3

共 14 条

[11] Living polymerization of 1-hexene due to an extra donor arm on a novel amine bis(phenolate) titanium catalyst
Tshuva, EY
Goldberg, I
Kol, M
Goldschmidt, Z
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (11) : 611 - 614
[12] Titanium complexes of chelating dianionic amine bis(phenolate) ligands: an extra donor makes a big difference
Tshuva, EY
Versano, M
Goldberg, I
Kol, M
Weitman, H
Goldschmidt, Z
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (08) : 371 - 373
[13] Novel zirconium complexes of amine bis(phenolate) ligands. Remarkable reactivity in polymerization of hex-1-ene due to an extra donor arm
Tshuva, EY
Goldberg, I
Kol, M
Weitman, H
Goldschmidt, Z
[J]. CHEMICAL COMMUNICATIONS, 2000, (05) : 379 - 380
[14] ATRANES - NEW EXAMPLES WITH UNEXPECTED PROPERTIES
VERKADE, JG
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (09) : 483 - 489

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