Fabrication and Mechanical Characterization of Calcium Alginate Fiber-Reinforced Polyvinyl Alcohol Based Composites

被引:10
作者
Dey, Kamol [1 ]
Khan, Ruhul A. [2 ]
Chowdhury, A. M. Sarwaruddin [1 ]
机构
[1] Univ Dhaka, Fac Engn & Technol, Dept Appl Chem & Chem Engn, Dhaka 1000, Bangladesh
[2] Bangladesh Atom Energy Commiss, Inst Nucl Sci & Technol, Nucl & Radiat Chem Div, Dhaka, Bangladesh
关键词
Alginate fiber; Composites; Interfacial properties; Polyethylene oxide; POLYPROPYLENE COMPOSITES; INTERFACIAL PROPERTIES; GAMMA-RADIATION; BLEND FIBERS; DEGRADATION; POLYMERS; ADHESION;
D O I
10.1080/03602559.2010.551390
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Calcium alginate fibers were prepared from sodium alginate by extruding aqueous sodium alginate solution (4% by weight) into a calcium chloride (2% by weight) bath. Water uptake and mechanical properties of the calcium alginate fiber were investigated. Water uptake tests of calcium alginate showed that it absorbed 50% of water within a minute and indicated strong hydrophilic nature. Polyvinyl alcohol (PVA)-based calcium alginate fiber reinforced unidirectional composites (10% fiber by weight) were fabricated by compression molding. Tensile strength (TS), tensile modulus (TM), bending strength (BS), bending modulus (BM) and impact strength (IS) of the PVA matrix and the composite were evaluated. TS, BS, TM, and BM of the PVA matrix were found 10, 18, 320 and 532MPa, respectively. TS and BS of the PVA based composite were found to be 16 and 27MPa, respectively, which were 60 and 50% higher than that of the PVA matrix. TM and BM of the composite were found to be 620 and 1056MPa, respectively, which were improved by 94 and 98% over the matrix material. Degradation tests of the composites were performed for up to 2 months in soil medium and found that composites lost almost 50% of its original mechanical properties. The interfacial properties of the composite were also investigated by using the single fiber fragmentation test (SFFT).
引用
收藏
页码:698 / 704
页数:7
相关论文
共 30 条
[1]   Polypropylene Cellulose-Based Composites: The Effect of Bagasse Reinforcement and Polybutadiene Isocyanate Treatment on the Mechanical Properties [J].
Ashori, Alireza ;
Nourbakhsh, Amir .
JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 111 (04) :1684-1689
[2]  
Carbal FS, 2003, POLYM TEST, V22, P907
[3]   ADHESION OF GRAPHITE FIBERS TO EPOXY MATRICES .2. THE EFFECT OF FIBER FINISH [J].
DRZAL, LT ;
RICH, MJ ;
KOENIG, MF ;
LLOYD, PF .
JOURNAL OF ADHESION, 1983, 16 (02) :133-152
[4]   Preparation and characterization of alginate/gelatin blend fibers [J].
Fan, LH ;
Du, YM ;
Huang, RH ;
Wang, Q ;
Wang, XH ;
Zhang, LN .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 96 (05) :1625-1629
[5]   Structure and properties of blend fibers prepared from alginate and konjac glucomannan [J].
Fan, Lihong ;
Zhu, Huibin ;
Zheng, Hua ;
Xu, Yongmei ;
Zhang, Chaocan .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (06) :3903-3907
[6]   Influence of natural fiber type in eco-composites [J].
Garcia, Miriam ;
Garmendia, Izaskun ;
Garcia, Javier .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (05) :2994-3004
[7]   Development of a single fiber fragmentation test for high strain rates [J].
Greenfield, MJ ;
Pedicini, A ;
Penn, LS .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 2000, 20 (05) :403-407
[8]   Effect of crosslinking monomers on the physico-mechanical and degradation properties of photografted chitosan film [J].
Haque, P. ;
Mustafa, A. I. ;
Khan, Mubarak A. .
CARBOHYDRATE POLYMERS, 2007, 68 (01) :109-115
[9]  
IDICULA M, 2009, J REINFOR PLAST COMP
[10]   TENSILE PROPERTIES OF FIBRE-REINFORCED METALS - COPPER/TUNGSTEN AND COPPER/MOLYBDENUM [J].
KELLY, A ;
TYSON, WR .
JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS, 1965, 13 (06) :329-&