Solid-phase microextraction-gas chromatography mass spectrometry and multivariate analysis for the characterization of roasted coffees

被引:45
作者
Zambonin, CG
Balest, L
De Benedetto, GE
Palmisano, F
机构
[1] Univ Bari, Dipartimento Chim, I-70126 Bari, Italy
[2] Univ Lecce, Dipartimento Beni Arti & Storia, I-73100 Lecce, Italy
关键词
solid-phase microextraction; headspace-SPME; GC-MS; principal component analysis; coffee;
D O I
10.1016/j.talanta.2004.11.023
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
HS-SPME-GC-MS in combination with PCA was employed to discriminate different arabica/robusta blends having different geographical origins. HS-SPME confirmed to be an effective and reproducible sampling technique for routine characterization of coffees. In addition, the chemometric approach permitted to find parameters suitable for the differentiation of the different blends and the determination of the real quality of the products. Finally, the proposed methods have been successfully applied to some commercial coffee blends. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:261 / 265
页数:5
相关论文
共 22 条
[1]  
Alpendurada MD, 2000, J CHROMATOGR A, V889, P3
[2]   SOLID-PHASE MICROEXTRACTION WITH THERMAL-DESORPTION USING FUSED-SILICA OPTICAL FIBERS [J].
ARTHUR, CL ;
PAWLISZYN, J .
ANALYTICAL CHEMISTRY, 1990, 62 (19) :2145-2148
[3]   Volatile components of Grana Parmigiano-Reggiano type hard cheese [J].
Bellesia, F ;
Pinetti, A ;
Pagnoni, UM ;
Rinaldi, R ;
Zucchi, C ;
Caglioti, L ;
Palyi, G .
FOOD CHEMISTRY, 2003, 83 (01) :55-61
[4]   Solid-phase microextraction in pesticide residue analysis [J].
Beltran, J ;
López, FJ ;
Hernández, F .
JOURNAL OF CHROMATOGRAPHY A, 2000, 885 (1-2) :389-404
[5]   Headspace sorptive extraction (HSSE), stir bar sorptive extraction (SBSE), and solid phase microextraction (SPME) applied to the analysis of roasted arabica coffee and coffee brew [J].
Bicchi, C ;
Iori, C ;
Rubiolo, P ;
Sandra, P .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2002, 50 (03) :449-459
[6]   Characterization of roasted coffee and coffee beverages by solid phase microextraction - Gas chromatography and principal component analysis [J].
Bicchi, CP ;
Panero, OM ;
Pellegrino, GM ;
Vanni, AC .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (12) :4680-4686
[7]   Near- and mid-infrared spectroscopies in food authentication: Coffee varietal identification [J].
Downey, G ;
Briandet, R ;
Wilson, RH ;
Kemsley, EK .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1997, 45 (11) :4357-4361
[8]   Two-fibre solid-phase microextraction combined with gas chromatography-mass spectrometry for the analysis of volatile aroma compounds in cooked pork [J].
Elmore, JS ;
Mottram, DS ;
Hierro, E .
JOURNAL OF CHROMATOGRAPHY A, 2001, 905 (1-2) :233-240
[9]   Applications of solid-phase microextraction in food analysis [J].
Kataoka, H ;
Lord, HL ;
Pawliszyn, J .
JOURNAL OF CHROMATOGRAPHY A, 2000, 880 (1-2) :35-62
[10]   Optimisation of headspace solid-phase microextraction for the analysis of volatile phenols in wine [J].
Meijías, RC ;
Marín, RN ;
Moreno, MDG ;
Barroso, CG .
JOURNAL OF CHROMATOGRAPHY A, 2003, 995 (1-2) :11-20