Bis(2,2′-bipyridine-N,N′)dicyanoiron(III) nitrate

被引：4
作者：
Poulsen, RD [1 ]
Hazell, A [1 ]
机构：
[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801005918
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Fe atom of the title compound, [Fe(bipy)(2)(CN)(2)O](NO3) (bipy is 2,2'-bipyridine, C10H8N2), is octahedrally coordinated to the N atoms of the bipyridines and to the C atoms of the cyanide groups which are cis to each other. The Fe-C distances are 1.922 (3) and 1.923 (2) Angstrom, and the Fe-N bonds trans to CN are 1.972 (2) and 1.973 (2) Angstrom and are longer than those cis to the CN groups, viz. 1.955 (2) and 1.962 (2) Angstrom. The bipyridine groups are close to being planar, with N-C-C-N torsion angles of -2.4 (3) and 1.6 (3)degrees, and bite angles of 81.43 (8) and 81.74 (8)degrees.
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收藏
页码：M186 / M187
页数：2
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