PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response

被引：73

作者：

Sun, Chuan-Fu ^{[1
]}

Hu, Chun-Li ^{[1
]}

Mao, Jiang-Gao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 35期

关键词：

NONLINEAR-OPTICAL MATERIALS; BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; 2ND-HARMONIC GENERATION; NLO PROPERTIES; HYDROTHERMAL PREPARATION; IODATE; RB; METAL; CATIONS;

D O I：

10.1039/c2cc30326d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polar material containing two types of stereoactive lone-pairs has been synthesized. The unique parallel alignment of the stereoactive lone-pairs on Pb2+ cations and the synergistic effect of two types of stereoactive lone-pairs on I5+ and Pb2+ cations make it exhibit a very large second-harmonic generation response of about 8 x KDP (KH2PO4).

引用

页码：4220 / 4222

页数：3

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