Chemical constituents from the roots of Xanthium sibiricum

被引：74

作者：

Kan, Suqin ^{[1
]}

Chen, Guangying ^{[1
]}

Han, Changri ^{[1
]}

Chen, Zhong ^{[2
]}

Song, Xinming ^{[1
]}

Ren, Ming ^{[1
]}

Jiang, Hong ^{[1
]}

机构：

[1] Hainan Normal Univ, Key Lab Trop Med Plant Chem, Minist Educ, Coll Chem & Chem Engn, Haikou 571158, Peoples R China

[2] Hainan Normal Univ, Coll Life Sci, Haikou 571158, Peoples R China

来源：

NATURAL PRODUCT RESEARCH | 2011年 / 25卷 / 13期

关键词：

Xanthium sibiricum; compositae; coumarinolignoids; chemotaxonomic markers; anti-peritonitis activity; CLEOME-VISCOSA SEEDS; CLEOMISCOSIN-A; STRUMARIUM; LIGNOIDS;

D O I：

10.1080/14786419.2010.539182

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Xanthium sibiricum patrin ex Widder (Compositae) is an annual herb which grows all around China. Chemical investigations of its roots resulted in the identification of 15 compounds: stigmast-4-en-6 beta-ol-3-one (1), beta-sitostenone (2), beta-sitosterol (3), nonadecanoic acid (4), 5 alpha,8 alpha-epidioxy-22E-ergosta- 6,22-dien-3 beta-ol (5), scopoletin (6), Jatrocin B (7), (+/-)syringaresinol (8), 9,9'-O-di-(E)-feruloyl-(-)-secoisolariciresinol (9), cleomiscosin A (10), cleomiscosin C (11), N-trans-feruloyl tyramine (12), daucosterol (13), 5-methyluracil (14) and uracil (15). Structures were elucidated by spectroscopic (NMR and MS) methods and confirmed by comparing with reference samples and literature data. Compounds 1-2, 4-12, 14, and 15 were isolated from this genus for the first time, while this is the first report of coumarinolignoids in the Compositae family, and coumarinoligoids could be considered as valuable chemotaxonomic markers for the plant.

引用

页码：1243 / 1249

页数：7

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