Crystal structure and thermal behavior of two new organic monosulfates NH3(CH2)5NH3SO4 1.5H2O and NH3(CH2)9NH3SO4 H2O

被引：5
|
作者：
Belhouchet, M [1 ]
Savariault, JM
Mhiri, T
机构：
[1] Univ Sfax, Fac Sci Sfax, Lab Etat Solide, Sfax 3018, Tunisia
[2] CNRS, Ctr Elaborat Mat & Etudes Struct, Toulouse, France
来源：
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2005年 / 66卷 / 07期
关键词：
organic compounds; differential scanning calorimetry (DSC); thermograrimetric analysis (TGA); crystal structure;
D O I：
10.1016/j.jpcs.2005.04.010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chemical preparation, the calorimetric studies and the crystal structure are given for two new organic sulfates NH3(CH2)(5)NH3SO4 1.5H(2)O (DAP-S) and NH3(CH2)(9)(NH3SO4H2O)-H-. (DAN-S). DAP-S is monoclinic P2(1)/n with unit cell dimensions: a = 11.9330(2) angstrom; b=10.9290(2) angstrom; c=17.5260(2) angstrom; beta=101.873(1)degrees; V=2236.77(6) angstrom(3); and Z=8. Its atomic arrangement is described as inorganic layers of SO42- units and water molecules separated by organic chains. DAN-S is monoclinic P2(1)/c with unit cell parameters: a=5.768(2) angstrom; b= 25.890(10) angstrom; c=11.177(5) angstrom; 0=115.70(4)degrees; V=1504.0(11) and Z=4. Its structure exhibits infinite chains, parallel to the [100] direction where the organic cations are interconnected. In both structures a network of strong and weak hydrogen bonds connects the different components in the building of the crystal. (c) 2005 Elsevier Ltd. All rights reserved.
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页码：1294 / 1301
页数：8
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