Total synthesis of (±) Xyloketal H

被引：5

作者：

Bhosale, Viraj A. ^{[1
]}

Kulkarni, Mukund G. ^{[1
]}

机构：

[1] Savitribai Phule Pune Univ, Dept Chem, Pune 411007, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 20期

关键词：

Claisen rearrangement; Grignard; Oxidation; Ozonolysis; Wittig olefination; FUNGUS XYLARIA SP; METHIDE INTERMEDIATE GENERATION; NATURAL-PRODUCTS; BIOMIMETIC SYNTHESIS; EFFICIENT METHOD; METABOLITE; CORE;

D O I：

10.1016/j.tetlet.2015.03.118

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient total synthesis of (+/-) Xyloketal H is described, the Wittig olefination-Claisen rearrangement protocol has served here as the key transformation for constructing the core structure of the metabolite. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2568 / 2570

页数：3

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