Preparation and properties of Ba1-xSrxTiO3 thin films deposited by the sol-gel technique

被引:1
作者
Dien, E [1 ]
Verveur, R [1 ]
Lejeune, M [1 ]
Smith, A [1 ]
机构
[1] Ecole Natl Super Ceram Ind, Lab Mat Ceram & Traitements Surface, ESA 6015, F-87065 Limoges, France
来源
JOURNAL DE PHYSIQUE IV | 1998年 / 8卷 / P9期
关键词
D O I
10.1051/jp4:1998912
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The present work concerns the preparation and the physical properties of Ba0.67Sr0.33TiO3 composition under thin film form. The layers have been deposited by spin-coating on top of Pt/Ti/SiO2/Si substrates using barium and strontium acetates, dissolved in acetic acid, mixed up with titanium tetra-isopropoxide in 2-propanol. The amounts of each constituent have been carefully adjusted to obtain stable and homogeneous sols. Different thermal treatments of the deposited layers have been carried out. They consist of a pre-firing cycle (330 degrees C or 550 degrees C) followed by a rapid thermal annealing (RTA) at 800 degrees C. The final films are characterized by a thickness in the range 180-600 nm and an average crystallite size of 40 nm. This paper also presents the electrical characteristics of the deposits. So far, the best dielectric constant, epsilon(r), is of the order of 350. Variations of epsilon' and epsilon " with respect to temperature (from -20 degrees C to 120 degrees C) have been investigated.
引用
收藏
页码:73 / 77
页数:5
相关论文
共 9 条
[1]   Factors controlling carbon retention in YBa2Cu3O7-delta [J].
Cazy, E ;
Khalfi, A ;
Smith, DS ;
Bonnett, JP .
JOURNAL OF MATERIALS RESEARCH, 1997, 12 (06) :1451-1455
[2]   HYDROLYSIS OF TITANIUM ALKOXIDES - MODIFICATION OF THE MOLECULAR PRECURSOR BY ACETIC-ACID [J].
DOEUFF, S ;
HENRY, M ;
SANCHEZ, C ;
LIVAGE, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 89 (1-2) :206-216
[3]   THIN-LAYER DIELECTRICS IN THE PB[(MG1/3NB2/3)1-XTIX]O3 SYSTEM [J].
FRANCIS, LF ;
PAYNE, DA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (12) :3000-3010
[4]   FILM THICKNESS DEPENDENCE OF DIELECTRIC-PROPERTIES OF BATIO3 THIN-FILMS PREPARED BY SOL-GEL METHOD [J].
HAYASHI, T ;
OJI, N ;
MAIWA, H .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (9B) :5277-5280
[5]  
Kulwicki B. M., 1992, P 8 IEEE INT S APPL, P1
[6]  
SANCHEZ C, 1990, MATER RES SOC SYMP P, V180, P47, DOI 10.1557/PROC-180-47
[7]   CRYSTALLOGRAPHIC AND ELECTRICAL-PROPERTIES OF EPITAXIAL BATIO3 FILM GROWN ON CONDUCTIVE AND INSULATING PEROVSKITE OXIDES [J].
WATANABE, Y ;
MATSUMOTO, Y ;
KUNITOMO, H ;
TANAMURA, M ;
NISHIMOTO, E .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1994, 33 (9B) :5182-5186
[8]   Uncooled IR imaging: Hybrid and integrated bolometer arrays [J].
Watton, R ;
Manning, PA ;
Perkins, MCJ ;
Gillham, JP ;
Todd, MA .
INFRARED TECHNOLOGY AND APPLICATIONS XXII, 1996, 2744 :486-499
[9]   FERROELECTRIC MATERIALS FOR THERMAL IR DETECTORS [J].
WHATMORE, RW ;
OSBOND, PC ;
SHORROCKS, NM .
FERROELECTRICS, 1987, 76 (3-4) :351-367