Attenuated Organomagnesium Activation of White Phosphorus

被引：43

作者：

Arrowsmith, Merle ^{[1
]}

Hill, Michael S. ^{[1
]}

Johnson, Andrew L. ^{[1
]}

Kociok-Koehn, Gabriele ^{[1
]}

Mahon, Mary F. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

cluster compounds; magnesium; P-4; activation; phosphorus; structure elucidation; ELEMENTAL PHOSPHORUS; ORGANOMETALLIC COMPLEXES; P-4; ACTIVATION; CAGE; FUNCTIONALIZATION; REACTIVITY; CATALYSIS; CLUSTERS; CALCIUM; ALKYL;

D O I：

10.1002/anie.201503065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sequential reactions between a 2,6-diisopropylphenyl-substituted -diketiminato magnesium n-butyl derivative and P-4 allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2-) and [nBu(2)P(8)](2-) cluster dianions.

引用

页码：7882 / 7885

页数：4

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