Attenuated Organomagnesium Activation of White Phosphorus

被引：43
作者：
Arrowsmith, Merle [1 ]
Hill, Michael S. [1 ]
Johnson, Andrew L. [1 ]
Kociok-Koehn, Gabriele [1 ]
Mahon, Mary F. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 27期
基金：
英国工程与自然科学研究理事会;
关键词：
cluster compounds; magnesium; P-4; activation; phosphorus; structure elucidation; ELEMENTAL PHOSPHORUS; ORGANOMETALLIC COMPLEXES; P-4; ACTIVATION; CAGE; FUNCTIONALIZATION; REACTIVITY; CATALYSIS; CLUSTERS; CALCIUM; ALKYL;
D O I：
10.1002/anie.201503065
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sequential reactions between a 2,6-diisopropylphenyl-substituted -diketiminato magnesium n-butyl derivative and P-4 allow the highly discriminating synthesis of unusual [nBu(2)P(4)](2-) and [nBu(2)P(8)](2-) cluster dianions.
引用
收藏
页码：7882 / 7885
页数：4
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