α-bond stretching:: A static approach for dynamic process

被引：76

作者：

Scheschkewitz, D

Amii, H

Gornitzka, H

Schoeller, WW

Bourissou, D

Bertrand, G ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, CNRS, UMR 2282,Joint Res Chem Lab, Riverside, CA 92521 USA

[2] Univ Toulouse 3, CNRS, UMR 5069, Lab Heterochim Fondamentale & Appliquee, F-31062 Toulouse 04, France

[3] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 05期

关键词：

boron; heterocycles; phosphorus; radicals; substituent effects;

D O I：

10.1002/anie.200352944

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ring stretching: The reaction profile corresponding to the inversion of bicyclo[1.1.0] butane derivatives, including the cyclobutane-1,3-diyl transition state, has been modeled by the preparation of a series of boron-phosphorus-containing analogues (see picture: P red; B blue). These differ only in the substituents around the B2P2 core, yet a variation of 40% in the boron-boron separation is observed.

引用

页码：585 / 587

页数：3

共 32 条

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