Structural response of titanate pyrochlores to swift heavy ion irradiation

The structure, size, and morphology of ion tracks resulting from irradiation of five different pyrochlore compositions (A(2)Ti(2)O(7), A = Yb, Er, Y, Gd, Sm) with 2.2 GeV Au-197 ions were investigated by means of synchrotron X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Radiation-induced amorphization occurred in all five materials analyzed following an exponential rate as a function of ion fluence. XRD patterns showed a general trend of increasing susceptibility of amorphization with increasing ratio of A- to B-site cation ionic radii (r(A)/r(B)) with the exception of Y2Ti2O7 and Sm2Ti2O7. This indicates that the track size does not necessarily increase with r(A)/r(B), in contrast with results from previous swift heavy ion studies on Gd2Zr2-xTixO7 pyrochlore materials. For Y2Ti2O7, this effect is attributed to the significantly lower electron density of this material relative to the lanthanide bearing pyrochlores, thus lowering the electronic energy loss (dE/dx) of the high-energy ions in this composition. An energy loss normalization procedure was performed which reveals an initial increase of amorphous track size with rA/rB that saturates above a cation radius ratio larger than Gd2Ti2O7. This is in agreement with previous low-energy ion irradiation experiments and first principles calculations of the disordering energy of titanate pyrochlores indicating that the same trends in disordering energy apply to radiation damage induced in both the nuclear and electronic energy loss regimes. HRTEM images indicate that single ion tracks in Yb2Ti2O7 and Er2Ti2O7, which have small A-site cations and low r(A)/r(B), exhibit a core-shell structure with a small amorphous core surrounded by a larger disordered shell. In contrast, single tracks in Gd2Ti2O7 and Sm2Ti2O7, have a larger amorphous core with minimal disordered shells. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.