Synthesis of the 1-hydroxy-closo-decaborate anion [1-B10H9OH]2-

被引：21

作者：

Bragin, VI

Sivaev, IB

Bregadze, VI

Votinova, NA

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] MV Lomonosov Fine Chem Technol Inst, Moscow 117571, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 11期

关键词：

closo-decaborate; derivatization; hydroxy derivative; diazonium derivative;

D O I：

10.1016/j.jorganchem.2005.01.053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the diazonium derivative of closo-decaborate anion with oxygen nucleophiles were studied. The reaction of [1-B10H9N2](-) with hydroxide ion gives the corresponding hydroxy derivative [1-B10H9OH](2-) in high yield. The reactions with OR (R = Me, Et, i-Pr, Ph) result in mixture of [I-B10H9OR](2)- and [a(2) -B20H18](4-). (c) 2005 Elsevier B.V. All rights reserved.

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页码：2847 / 2849

页数：3

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