Synthesis of the 1-hydroxy-closo-decaborate anion [1-B10H9OH]2-

被引：21

作者：

Bragin, VI

Sivaev, IB

Bregadze, VI

Votinova, NA

机构：

[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[2] MV Lomonosov Fine Chem Technol Inst, Moscow 117571, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 11期

关键词：

closo-decaborate; derivatization; hydroxy derivative; diazonium derivative;

D O I：

10.1016/j.jorganchem.2005.01.053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of the diazonium derivative of closo-decaborate anion with oxygen nucleophiles were studied. The reaction of [1-B10H9N2](-) with hydroxide ion gives the corresponding hydroxy derivative [1-B10H9OH](2-) in high yield. The reactions with OR (R = Me, Et, i-Pr, Ph) result in mixture of [I-B10H9OR](2)- and [a(2) -B20H18](4-). (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2847 / 2849

页数：3

共 18 条

[1] REACTION OF B10H10-2 WITH ARYLDIAZONIUM SALTS
HAWTHORNE, MF
OLSEN, FP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (11) : 2366 - +
[2] THE ROLE OF CHEMISTRY IN THE DEVELOPMENT OF BORON NEUTRON-CAPTURE THERAPY OF CANCER
HAWTHORNE, MF
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (07): : 950 - 984
[3] Synthesis, spectroscopic characterization, and structure of closo-1,10-B10H3F22- and related fluorinated derivatives of B10H102-
Ivanov, SV
Ivanova, SM
Miller, SM
Anderson, OP
Kuznetsov, NT
Solntsev, KA
Strauss, SH
[J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1997, 62 (08) : 1310 - 1324
[4] Organic derivatives of closo-boranes:: a new class of liquid crystal materials
Kaszynski, P
Douglass, AG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 581 (1-2) : 28 - 38
[5] REGIOSELECTIVE SYNTHESIS OF [1-B10H9(SH)]2- AND [2-B10H9(SH)]2- - POTENTIAL AGENTS FOR BORON NEUTRON-CAPTURE THERAPY OF BRAIN-TUMORS
KOMURA, M
NAKAI, H
SHIRO, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08): : 1953 - 1956
[6] NOVEL TRANSFER OF DIAZONIUM FUNCTION FROM CARBON TO BORON
LEYDEN, RN
HAWTHORN.MF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (06) : 2032 - 2033
[7] SYNTHESIS OF DIAZONIUM DERIVATIVES OF B10H102- FROM ARYLAZO INTERMEDIATES
LEYDEN, RN
HAWTHORNE, MF
[J]. INORGANIC CHEMISTRY, 1975, 14 (10) : 2444 - 2446
[8] Malinina EA, 2002, RUSS J INORG CHEM+, V47, P1158
[9] Thermal stability of the diazohydroborate [1-N2B10H9]-:: degradation to [B20H18]2- anion
Naoufal, D
Bonnetot, B
Mongeot, H
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (04) : 244 - 246
[10] Replacement of the nitrogen of [1-N2B10H9]- by amines or nitriles, a route to hydrophobic monoanions
Naoufal, D
Grüner, B
Bonnetot, B
Mongeot, H
[J]. POLYHEDRON, 1999, 18 (07) : 931 - 939

← 1 2 →