Terapascal static pressure generation with ultrahigh yield strength nanodiamond

被引:160
作者
Dubrovinskaia, Natalia [1 ]
Dubrovinsky, Leonid [2 ]
Solopova, Natalia A. [1 ,2 ]
Abakumov, Artem [3 ,9 ]
Turner, Stuart [3 ]
Hanfland, Michael [4 ]
Bykova, Elena [2 ]
Bykov, Maxim [2 ]
Prescher, Clemens [5 ]
Prakapenka, Vitali B. [5 ]
Petitgirard, Sylvain [2 ]
Chuvashova, Irina [1 ,2 ]
Gasharova, Biliana [6 ]
Mathis, Yves-Laurent [7 ]
Ershov, Petr [8 ]
Snigireva, Irina [4 ]
Snigirev, Anatoly [4 ,8 ]
机构
[1] Univ Bayreuth, Crystallog Lab, Mat Phys & Technol Extreme Condit, D-95440 Bayreuth, Germany
[2] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
[3] Univ Antwerp, Electron Microscopy Mat Sci EMAT, Groenenborgerlaan 171, B-2020 Antwerp, Belgium
[4] European Synchrotron Radiat Facil, BP 220, F-38043 Grenoble, France
[5] Univ Chicago, Ctr Adv Radiat Sources, Chicago, IL 60437 USA
[6] Karlsruhe Inst Technol, Inst Photon Sci & Synchrotron Radiat, POB 3640, D-76021 Karlsruhe, Germany
[7] Karlsruhe Inst Technol, ANKA Synchrotron Radiat, POB 3640, D-76021 Karlsruhe, Germany
[8] Immanuel Kant Balt Fed Univ, RU-236041 Kaliningrad, Russia
[9] Skolkovo Inst Sci & Technol, Ctr Electrochem Energy Storage, Moscow 143026, Russia
来源
SCIENCE ADVANCES | 2016年 / 2卷 / 07期
关键词
POLYCRYSTALLINE DIAMOND; X-RAY; DIFFRACTION; COMPRESSION; ELASTICITY; HARDNESS; CARBONS; ANVILS; PHASE;
D O I
10.1126/sciadv.1600341
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Studies of materials' properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (similar to 460 GPa at a confining pressure of similar to 70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications.
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页数:12
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