Synthesis of poly(butyl acrylate) using an electrochemically mediated atom transfer radical polymerization

被引：4
|
作者：
Chmielarz, Pawel [1 ]
Sobkowiak, Andrzej [1 ]
机构：
[1] Rzeszow Tech Univ, Wydzial Chem, Al Powstancow Warszawy 6, PL-35959 Rzeszow, Poland
来源：
POLIMERY | 2016年 / 61卷 / 09期
关键词：
electrochemically mediated ATRP; homopolymers; poly(butyl acrylate); ARGET ATRP; BLOCK-COPOLYMERS; CATALYST; COPPER;
D O I：
10.14314/polimery.2016.585
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(butyl acrylate) homopolymers were prepared via electrochemically mediated atom transfer radical polymerization (eATRP) using only 10 ppm concentration of Cu(II) complex catalyst, lower than commonly reported 50-400 ppm. The results of chromatographic analysis (GPC) indicate that the formation of polyacrylates proceeded via ATRP mechanism. H-1 NMR spectra confirm the chemical structure of the synthesized homopolymers.
引用
收藏
页码：585 / 590
页数：6
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