Synthesis of poly(butyl acrylate) using an electrochemically mediated atom transfer radical polymerization

被引：4

作者：

Chmielarz, Pawel ^{[1
]}

Sobkowiak, Andrzej ^{[1
]}

机构：

[1] Rzeszow Tech Univ, Wydzial Chem, Al Powstancow Warszawy 6, PL-35959 Rzeszow, Poland

来源：

POLIMERY | 2016年 / 61卷 / 09期

关键词：

electrochemically mediated ATRP; homopolymers; poly(butyl acrylate); ARGET ATRP; BLOCK-COPOLYMERS; CATALYST; COPPER;

D O I：

10.14314/polimery.2016.585

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(butyl acrylate) homopolymers were prepared via electrochemically mediated atom transfer radical polymerization (eATRP) using only 10 ppm concentration of Cu(II) complex catalyst, lower than commonly reported 50-400 ppm. The results of chromatographic analysis (GPC) indicate that the formation of polyacrylates proceeded via ATRP mechanism. H-1 NMR spectra confirm the chemical structure of the synthesized homopolymers.

引用

页码：585 / 590

页数：6

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