Visible light mediated chemo-selective oxidation of benzylic alcohols

被引：36

作者：

Devari, Shekaraiah ^{[1
]}

Rizvi, Masood Ahmad ^{[2
]}

Shah, Bhahwal Ali ^{[1
]}

机构：

[1] CSIR Indian Inst Integrat Med, Nat Product Microbes, Acad Sci & Innovat Res AcSIR, Canal Rd, Jammu 180001, India

[2] Univ Kashmir, Dept Chem, Srinagar, Jammu & Kashmir, India

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 30期

关键词：

Chemoselective oxidation; Eosin Y; TBHP; Photoredox; Visible light; C BOND-CLEAVAGE; AEROBIC OXIDATION; CHEMOSELECTIVE OXIDATION; MOLECULAR-OXYGEN; METAL-FREE; PHOTOCATALYTIC OXIDATION; ACETOPHENONE DERIVATIVES; ACRONYCHIA-PEDUNCULATA; ALPHA-KETOAMIDES; NATURAL-PRODUCTS;

D O I：

10.1016/j.tetlet.2016.06.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly chemoselective visible light mediated strategy has been developed for oxidation of benzylic alcohols. The method circumvents the use of toxic metal catalysts, high energy light source, and operates at room temperature. Furthermore reaction is easily scalable to gram levels. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：3294 / 3297

页数：4

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