Effect of Calcined MgO-rich Byproduct from the Extraction of Li2CO3 on the Performance of Magnesium Phosphate Cement

被引:6
作者
Chen, Wenhai [1 ]
Wu, Chengyou [1 ]
Yu, Hongfa [2 ]
Chen, Yuanji [1 ]
Zheng, Shuhai [1 ]
机构
[1] Qinghai Univ, Sch Civil Engn, Xining, Qinghai, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Dept Civil Engn, Nanjing, Jiangsu, Peoples R China
关键词
CHEMICALLY BONDED CERAMICS; CALCINATION TEMPERATURE; MECHANICAL-PROPERTIES; RAPID REPAIR; BORIC-ACID; CONCRETE; MORTAR; OXIDE;
D O I
10.3151/jact.15.749
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Magnesium phosphate cement was prepared with an MgO-containing byproduct (EL-MgO) obtained through the extraction of Li2CO3 from salt lakes, and was used to replace dead burnt MgO in magnesium phosphate cement (MPC) formulations. The properties of EL-MgO after calcination at various temperatures were investigated. Changes in pH, alternating-current impedance, and hydration-heat-release rate were assessed. Surface area and reactivity decreased while the degree of crystallization increased with increasing calcination temperature, resulting in longer setting times. The compressive strength of MPC prepared with EL-MgO calcined at 1000 degrees C was 53.9 MPa after 1 day, which is high for quick-repair materials.
引用
收藏
页码:749 / 759
页数:11
相关论文
共 30 条
[1]   THE CHEMICAL-COMPOSITION OF MORTARS MADE FROM MAGNESIA-PHOSPHATE CEMENT [J].
ABDELRAZIG, BEI ;
SHARP, JH ;
ELJAZAIRI, B .
CEMENT AND CONCRETE RESEARCH, 1988, 18 (03) :415-425
[2]   Effects of Calcination Temperature of Boron-Containing Magnesium Oxide Raw Materials on Properties of Magnesium Phosphate Cement as a Biomaterial [J].
Dong Jinmei ;
Yu Hongfa ;
Xiao Xueying ;
Li Ying ;
Wu Chengyou ;
Wen Jing ;
Tan Yongshan ;
Chang Chenggong ;
Zheng Weixin .
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2016, 31 (03) :671-676
[3]   Electrical characterization of aluminous cement at the early age in the 10 Hz-1 GHz frequency range [J].
El Hafiane, Y ;
Smith, A ;
Bonnet, JP ;
Abélard, P ;
Blanchart, P .
CEMENT AND CONCRETE RESEARCH, 2000, 30 (07) :1057-1062
[4]   Interaction between low-grade magnesium oxide and boric acid in chemically bonded phosphate ceramics formulation [J].
Formosa, J. ;
Chimenos, J. M. ;
Lacasta, A. M. ;
Niubo, M. .
CERAMICS INTERNATIONAL, 2012, 38 (03) :2483-2493
[5]   Characterisation of magnesium potassium phosphate cements blended with fly ash and ground granulated blast furnace slag [J].
Gardner, Laura J. ;
Bernal, Susan A. ;
Walling, Samuel A. ;
Corkhill, Claire L. ;
Provis, John L. ;
Hyatt, Neil C. .
CEMENT AND CONCRETE RESEARCH, 2015, 74 :78-87
[6]   Struvite-(K), KMgPO4•6H2O, the potassium equivalent of struvite - a new mineral [J].
Graeser, Stefan ;
Postl, Walter ;
Bojar, Hans-Peter ;
Berlepsch, Peter ;
Armbruster, Thomas ;
Raber, Thomas ;
Ettinger, Karl ;
Walter, Franz .
EUROPEAN JOURNAL OF MINERALOGY, 2008, 20 (04) :629-633
[7]   The effect of retarders on the microstructure and mechanical properties of magnesia-phosphate cement mortar [J].
Hall, DA ;
Stevens, R ;
El-Jazairi, B .
CEMENT AND CONCRETE RESEARCH, 2001, 31 (03) :455-465
[8]  
Hall DA, 1998, J AM CERAM SOC, V81, P1550
[9]  
Ibrahim W. A., 2011, The Journal of American Science, V7, P543
[10]   Strong and tough magnesium wire reinforced phosphate cement composites for load-bearing bone replacement [J].
Krueger, Reinhard ;
Seitz, Jan-Marten ;
Ewald, Andrea ;
Bach, Friedrich-Wilhelm ;
Groll, Juergen .
JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS, 2013, 20 :36-44