Micro-composites of poly(styrene) and nylon 3 by in-situ polymerization

被引:3
|
作者
Ann, J [1 ]
Rikukawa, M [1 ]
Sanui, K [1 ]
Ogata, N [1 ]
机构
[1] SAM YANG CO,SAM YANG R&D CTR,YUSUNG GU,TAEJON,SOUTH KOREA
关键词
micro composites; poly(styrene); nylon; 3; hydrogen bonding;
D O I
10.1295/polymj.28.496
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The in-situ polymerization of acrylamide in solutions of poly(styrene) (PSt) was carried out by amionic polymerization to form Nylon 3 in PSt as micro-composites in which Nylon 3 was dispersed as fine particles. Copolymers of styrene (St) and 4-vinylpyridine (4-VPy) were used as matrix polymers in order to improve a compatibility between the in-situ formed Nylon 3 and matrix polymer through hydrogen-bonding. These micro-composites showed great improvement of mechanical properties owing to reinforcement by ultra-fine particles of Nylon 3. Especially, the micro-composite derived from poly(St-co-4-VPy) showed excellent improvements of mechanical properties owing to the hydrogen bonding interactions between Nylon 3 and 4-VPy.
引用
收藏
页码:496 / 500
页数:5
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