Early-Transition-Metal Catalysts with Phenoxy-Imine-Type Ligands for the Oligomerization of Ethylene

被引：26
|
作者：
Kinoshita, Shinsuke [1 ]
Kawamura, Kazumori [1 ]
Fujita, Terunori [1 ]
机构：
[1] Mitsui Chem Inc, Res Ctr, Chiba 2990265, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 02期
关键词：
ethylene; multidentate ligands; olefins; oligomerization; transition metal complexes; OLEFIN POLYMERIZATION CATALYSTS; ZIRCONIUM COMPLEXES; FI CATALYSTS; ETHENE TRIMERIZATION; CHROMIUM CATALYSTS; OXIDATION-STATE; BEARING; DIMERIZATION; SYSTEM; DISCOVERY;
D O I：
10.1002/asia.201000563
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Early-transition-metal complexes incorporating phenoxy-imine-type bidentate and tridentate ligands, after activation, can achieve selective as well as nonselective ethylene oligomerization to produce 1-hexene, linear alpha-olefins, and vinyl-terminated low-molecular-weight polyethylenes, all with high efficiency.
引用
收藏
页码：284 / 290
页数：7
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