Synthesis, characterization of a novel calixarene having dipyridyl pendants and study of its complexes with Cu(II) and Co(II)

被引：34

作者：

Arena, G ^{[1
]}

Contino, A ^{[1
]}

Longo, E ^{[1
]}

Sciotto, D ^{[1
]}

Sgarlata, C ^{[1
]}

Spoto, G ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 29期

关键词：

calixarenes; cobalt(II); copper(II); spectrophotometric titrations;

D O I：

10.1016/S0040-4039(03)01319-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two dipyridyl pendants were attached to the 1,3 positions of a calix[4]arene, with the purpose of having a ligand able to complex Cu(II) and Co(II). Indeed, the new ligand, fixed in its 1,3-alternate conformation, forms stable complexes with both Co(II) and Cu(II), as shown by UV-vis titrations carried out in acetonitrile. However, the data analysis clearly shows that the ligand forms with the two metal ions complexes having different stoichiometries. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：5415 / 5418

页数：4

共 24 条

[1]

ARENA G, UNPUB

[2] CALIX[4]ARENE CRYPTAND AND NEW 1,3-BIS-PYRIDYL, 1,3-BIS-BIPYRIDYL AND 1,3-BIS-ALKYLTHIOETHER CALIX[4]ARENES DESIGNED TO COORDINATE TRANSITION-METAL CATIONS [J].

BEER, PD ;

MARTIN, JP ;

DREW, MGB .

TETRAHEDRON, 1992, 48 (45) :9917-9928

[3] Synthesis of calix[4]arene receptors incorporating (2,2'-bipyridin-6-yl)methyl and (9-methyl-1,10-phenanthrolin-2-yl)methyl chromophores and luminescence of their Eu3+ and Tb3+ complexes [J].

Casnati, A ;

Fischer, C ;

Guardigli, M ;

Isernia, A ;

Manet, I ;

Sabbatini, N ;

Ungaro, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (03) :395-399

[4]

Casnati A, 2001, CALIXARENES 2001, P365

[5]

Dalbavie JO, 2002, EUR J INORG CHEM, P901

[6]

Dalbavie JO, 2000, EUR J INORG CHEM, P683

[7] Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs [J].

Gans, P ;

Sabatini, A ;

Vacca, A .

TALANTA, 1996, 43 (10) :1739-1753

[8]

Gutsche C.D., 1989, MONOGRAPHS SUPRAMOLE

[9]

Gutsche C. D, 1998, MONOGRAPHS SUPRAMOLE

[10]

Job P, 1928, ANN CHIM FRANCE, V9, P113

← 1 2 3 →