Design of ruthenium/iron oxide nanoparticle mixtures for hydrogenation of nitrobenzene

被引：104

作者：

Easterday, R. ^{[1
]}

Sanchez-Felix, O. ^{[1
]}

Losovyj, Y. ^{[1
]}

Pink, M. ^{[1
]}

Stein, B. D. ^{[2
]}

Morgan, D. G. ^{[1
]}

Rakitin, M. ^{[3
]}

Doluda, V. Yu. ^{[3
]}

Sulman, M. G. ^{[3
]}

Mahmoud, W. E. ^{[4
]}

Al-Ghamdi, A. A. ^{[4
]}

Bronstein, Lyudmila M. ^{[1
,4
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Dept Biol, Bloomington, IN 47405 USA

[3] Tver State Tech Univ, Dept Biotechnol & Chem, Tver 170026, Russia

[4] King Abdulaziz Univ, Fac Sci, Dept Phys, Jeddah, Saudi Arabia

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2015年 / 5卷 / 03期

基金：

美国国家科学基金会; 俄罗斯基础研究基金会;

关键词：

SIZE-CONTROLLED SYNTHESIS; SELECTIVE HYDROGENATION; MAGNETIC NANOPARTICLES; REUSABLE CATALYST; ONE-POT; HYDROXIDE; PALLADIUM; EFFICIENT; NANOSPHERES; ACID;

D O I：

10.1039/c4cy01277a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Here we report novel catalysts for nitrobenzene hydrogenation based on Ru/RuO2 nanoparticles (NPs) and including iron oxide NPs, allowing magnetic recovery. The solvent type, reaction temperature, and the size and composition of initial iron oxide NPs are demonstrated to be the control factors determining synthesis outcomes including the degree of NP aggregation and catalytic properties. A complete characterization of the catalysts using transmission electron microscopy (TEM), X-ray powder diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and energy dispersive x-ray spectroscopy (EDS) allowed assessment of the structure-property relationships. It is revealed that coexistence of the Ru/RuO2 and iron oxide NPs in the catalyst as well as the proximity of two different NP types lead to significantly higher aniline yields and reaction rates. The catalytic properties are also influenced by the type of iron oxide NPs present in the catalytic samples.

引用

页码：1902 / 1910

页数：9

共 53 条

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