Systematic Study of Interfacial Interactions Between Clays and an Ionomer

To study the interfacial interactions between an ionomer [poly(ethylene-co-acrylic acid) neutralized by zinc salts (PI)] and clays, PI-clay nanocomposites were prepared using a solution method. Two types of commercially available montmorillonite clays respectively K10 and KSF were used, and were modified with organic modifiers with chain lengths of 12-18 carbons. The interactions between the PI, clays, and modifiers were evaluated through study of the structure, morphology, and properties of the PI-clay nanocomposites. We found that the modifiers were successfully intercalated into the clay layers (Fourier transform infrared spectroscopy). The clay modified with a long-chain agent showed an exfoliated nature in the nanocomposite. The thermal stability and storage modulus of PI were improved greatly by the addition of the clays, especially when the long-chain modifier was used (thermogravimetric analysis and dynamic mechanical analysis). The differential scanning calorimetry results show that clay layers are inserted into the clusters because of solvent-directed morphological evolution, so the transition of the ionic domains and the crystallinity of PI are changed. The interaction between PI, the modifier, and the silicate layer played an important role in the determination of the properties of the nanocomposites. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 3395-3405, 2010