Synthesis, characterization, and reactivity of a new mononuclear benzyl-cobalt complex containing mixed tridentate imino-oxime and diamine ligands

被引：9

作者：

Dreos, R ^{[1
]}

Herlinger, E ^{[1
]}

Tauzher, G ^{[1
]}

Vuano, S ^{[1
]}

Nardin, G ^{[1
]}

Randaccio, L ^{[1
]}

机构：

[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 11期

关键词：

D O I：

10.1021/om970967k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [C6H5CH2Co(L)(LR)]ClO4 (3), where L = 2-((2-pyridylethyl)imino)-3-butanone oximato and LR = 2-((2-pyridylethyl)amino)-3-aminobutane has been prepared by reduction, with NaBH4 of the complex [Co-III(L)(2)]ClO4, followed by addition of C6H5CH2Cl. The compounds was characterized in the solid state by X-ray analysis. The complex undergoes Co-C homolytic cleavage under acidic conditions, giving dibenzyl under a nitrogen atmosphere and benzaldehyde in the presence of air.

引用

页码：2366 / 2369

页数：4

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