Interfacial Synthesis of Conjugated Two-Dimensional N-Graphdiyne

被引：130

作者：

Kan, Xiaonan ^{[1
]}

Ban, Yanqi ^{[1
]}

Wu, Chenyu ^{[2
]}

Pan, Qingyan ^{[1
]}

Liu, Hui ^{[1
]}

Song, Jianhui ^{[1
]}

Zuo, Zicheng ^{[3
]}

Li, Zhibo ^{[1
]}

Zhao, Yingjie ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Sch Polymer Sci & Engn, Shandong Prov Educ Dept, Key Lab Biobased Polymer Mat, Qingdao 266042, Peoples R China

[2] Univ New South Wales, Sch Chem Engn, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

[3] Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 01期

基金：

中国国家自然科学基金;

关键词：

graphdiyne; two-dimensional materials; N-doping; interfacial synthesis; diine; THEORETICAL PREDICTIONS; AIR/WATER INTERFACE; ORGANIC FRAMEWORK; POLYMER; CHEMISTRY; GRAPHYNE; STORAGE; SCALE;

D O I：

10.1021/acsami.7b17326

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We explored the interfacial synthesis of 2D N-graphdiyne films at the gas/liquid and liquid/liquid interfaces. Triazine- or pyrazine-based monomers containing ethynyl group were polymerized through the Glaser coupling reactions at interfaces. Several layered, highly ordered and conjugated 2D N-graphdiyne were obtained. Their structures were characterized by TEM, SEM, AFM, XPS, and Raman spectra. Thin films with minimum thickness of 4 nm could be prepared.

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收藏

页码：53 / 58

页数：6

相关论文

共 28 条

[1] Free-Standing, Single-Monomer-Thick Two-Dimensional Polymers through Covalent Self-Assembly in Solution [J].

Baek, Kangkyun ;

Yun, Gyeongwon ;

Kim, Youngkook ;

Kim, Dongwoo ;

Hota, Raghunandan ;

Hwang, Ilha ;

Xu, Dan ;

Ko, Young Ho ;

Gu, Gil Ho ;

Suh, Ju Hyung ;

Park, Chan Gyung ;

Sung, Bong June ;

Kim, Kimoon .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (17) :6523-6528

[2] Two-Dimensional Polymer Formation on Surfaces: Insight into the Roles of Precursor Mobility and Reactivity [J].

Bieri, Marco ;

Nguyen, Manh-Thuong ;

Groening, Oliver ;

Cai, Jinming ;

Treier, Matthias ;

Ait-Mansour, Kamel ;

Ruffieux, Pascal ;

Pignedoli, Carlo A. ;

Passerone, Daniele ;

Kastler, Marcel ;

Muellen, Klaus ;

Fasel, Roman .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (46) :16669-16676

[3] Synthesis and electronic structure of a two dimensional π-conjugated polythiophene [J].

Cardenas, Luis ;

Gutzler, Rico ;

Lipton-Duffin, Josh ;

Fu, Chaoying ;

Brusso, Jaclyn L. ;

Dinca, Laurentiu E. ;

Vondracak, Martin ;

Fagot-Revurat, Yannick ;

Malterre, Daniel ;

Rosei, Federico ;

Perepichka, Dmitrii F. .

CHEMICAL SCIENCE, 2013, 4 (08) :3263-3268

[4] Rationally synthesized two-dimensional polymers [J].

Colson, John W. ;

Dichtel, William R. .

NATURE CHEMISTRY, 2013, 5 (06) :453-465

[5] Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene [J].

Colson, John W. ;

Woll, Arthur R. ;

Mukherjee, Arnab ;

Levendorf, Mark P. ;

Spitler, Eric L. ;

Shields, Virgil B. ;

Spencer, Michael G. ;

Park, Jiwoong ;

Dichtel, William R. .

SCIENCE, 2011, 332 (6026) :228-231

[6] Synthesis of a Two-Dimensional Covalent Organic Monolayer through Dynamic Imine Chemistry at the Air/Water Interface [J].

Dai, Wenyang ;

Shao, Feng ;

Szczerbinski, Jacek ;

McCaffrey, Ryan ;

Zenobi, Renato ;

Jin, Yinghua ;

Schlueter, A. Dieter ;

Zhang, Wei .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (01) :213-217

[7] Surface mediated synthesis of 2D covalent organic frameworks: 1,3,5-tris(4-bromophenyl)benzene on graphite(001), Cu(111), and Ag(110) [J].

Gutzler, Rico ;

Walch, Hermann ;

Eder, Georg ;

Kloft, Stephan ;

Heckl, Wolfgang M. ;

Lackinger, Markus .

CHEMICAL COMMUNICATIONS, 2009, (29) :4456-4458

[8] Graphyne: Hexagonal network of carbon with versatile Dirac cones [J].

Kim, Bog G. ;

Choi, Hyoung Joon .

PHYSICAL REVIEW B, 2012, 86 (11)

[9] A nanoporous two-dimensional polymer by single-crystal-to-single-crystal photopolymerization [J].

Kissel, Patrick ;

Murray, Daniel J. ;

Wulftange, William J. ;

Catalano, Vincent J. ;

King, Benjamin T. .

NATURE CHEMISTRY, 2014, 6 (09) :774-778

[10]

Kory MJ, 2014, NAT CHEM, V6, P779, DOI [10.1038/nchem.2007, 10.1038/NCHEM.2007]