Structurally Characterized Cationic Silver(I) and Ruthenium(II) Carbene Complexes of 1,2,3-Triazol-5-ylidenes

被引：67
作者：
Cai, Jiajia [1 ]
Yang, Xiaoping [1 ]
Arumugam, Kuppuswamy [1 ]
Bielawski, Christopher W. [1 ]
Sessler, Jonathan L. [1 ,2 ]
机构：
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 18期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
N-HETEROCYCLIC CARBENES; OPENING METATHESIS POLYMERIZATION; COORDINATION CHEMISTRY; TRANSFER HYDROGENATION; PALLADIUM COMPLEXES; OLEFIN METATHESIS; IMIDAZOLIUM SALTS; TERMINAL ALKYNES; WATER OXIDATION; LIGANDS;
D O I：
10.1021/om200670f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 1,3,4-substituted 1,2,3-triazolium salt was found to function as an effective precursor for the synthesis of the first structurally characterized cationic silver(I) and ruthenium(II) carbene complexes of overall 1:2 ligand-to-metal stoichiometry. The Ag(I) complex crystallized in the form of an eight silver atom containing cluster, whereas the Ru(II) complex proved to be a discrete species and was found to be capable of initiating the ring-opening metathesis polymerization of norbornene upon activation with (trimethylsilyl)diazomethane.
引用
收藏
页码：5033 / 5037
页数：5
相关论文
共 66 条
  • [21] Synthesis and characterization of N-heterocyclic carbene phospha-palladacycles and their properties in Heck catalysis
    Frey, GD
    Schütz, J
    Herdtweck, E
    Herrmann, WA
    [J]. ORGANOMETALLICS, 2005, 24 (18) : 4416 - 4426
  • [22] Ag(I) N-heterocyclic carbene complexes: Synthesis, structure, and application
    Garrison, JC
    Youngs, WJ
    [J]. CHEMICAL REVIEWS, 2005, 105 (11) : 3978 - 4008
  • [23] Glorius F., 2007, TOPICS ORGANOMETALLI, P21
  • [24] Transfer hydrogenation of imines and alkenes and direct reductive amination of aldehydes catalyzed by triazole-derived iridium(I) carbene complexes
    Gnanamgari, Dinakar
    Moores, Audrey
    Rajaseelan, Edward
    Crabtree, Robert H.
    [J]. ORGANOMETALLICS, 2007, 26 (05) : 1226 - 1230
  • [25] Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH5(PPh3)2
    Gründemann, S
    Kovacevic, A
    Albrecht, M
    Faller, JW
    Crabtree, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) : 10473 - 10481
  • [26] Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex
    Gründemann, S
    Kovacevic, A
    Albrecht, M
    Faller, JW
    Crabtree, RH
    [J]. CHEMICAL COMMUNICATIONS, 2001, (21) : 2274 - 2275
  • [27] Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)
    Guisado-Barrios, Gregorio
    Bouffard, Jean
    Donnadieu, Bruno
    Bertrand, Guy
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (28) : 4759 - 4762
  • [28] Heterocyclic carbenes: Synthesis and coordination chemistry
    Hahn, F. Ekkehardt
    Jahnke, Mareike C.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (17) : 3122 - 3172
  • [29] Synthesis of Silver(I) and Gold(I) Complexes with Cyclic Tetra- and Hexacarbene Ligands
    Hahn, F. Ekkehardt
    Radloff, Christian
    Pape, Tania
    Hepp, Alexander
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (35) : 10900 - 10904
  • [30] Preparation and characterization of the first pyrazole-based remote N-heterocyclic carbene complexes of palladium(II)
    Han, Yuan
    Huynh, Han Vinh
    [J]. CHEMICAL COMMUNICATIONS, 2007, (10) : 1089 - 1091
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