Experimental Study on Hydrothermal Carbonization of Lignocellulosic Biomass with Magnesium Chloride for Solid Fuel Production

被引:16
作者
Carrasco, Samuel [1 ]
Silva, Javier [1 ]
Pino-Cortes, Ernesto [1 ]
Gomez, Jaime [2 ,3 ]
Vallejo, Fidel [2 ,3 ]
Diaz-Robles, Luis [2 ,3 ]
Campos, Valeria [2 ,3 ]
Cubillos, Francisco [2 ,3 ]
Pelz, Stefan [4 ]
Paczkowski, Sebastian [4 ]
Cereceda-Balic, Francisco [5 ]
Vergara-Fernandez, Albero [6 ]
Lapuerta, Magin [7 ]
Pazo, Amparo [8 ]
Monedero, Esperanza [8 ]
Hoekman, Kent [9 ]
机构
[1] Pontificia Univ Catolica Valparaiso, Escuela Ingn Quim, Av Brasil 2162, Valparaiso 2362854, Chile
[2] Univ Santiago Chile, Dept Ingn Quim, Av Libertador Bernardo OHiggins 3363, Estacion Cent 9170022, Chile
[3] Programa Ctr Valorizac Residuos & Econ Circular, Av Libertador Bernardo OHiggins 3363, Estacion Cent 9170022, Chile
[4] Univ Appl Forest Sci Rottenburg, Inst Appl Res, Schadenweilerhof 1, D-72108 Rottenburg, Germany
[5] Univ Tecn Federico Santa Maria, Ctr Tecnol Ambientales, Gen Bari 699, Valparaiso 2390136, Chile
[6] Univ Andes, Fac Ingn & Ciencias Aplicadas, Monsenor Alvaro del Portillo 12455, Las Condes 7620001, Chile
[7] Univ Castilla La Mancha, Escuela Tecn Super Ingn Ind, Edificio Politecn,Avda Camilo Jose Cela S-N, Ciudad Real 13071, Spain
[8] Univ Castilla La Mancha, Inst Invest Energias Renovables, Albacete 02006, Spain
[9] Desert Res Inst, 2215 Raggio Pkwy, Reno, NV 89512 USA
关键词
hydrothermal carbonization; waste to energy; additives; lignocellulosic biomass; magnesium chloride; GRAPE POMACE; HTC; WASTE; TORREFACTION; COMBUSTION; TEMUCO;
D O I
10.3390/pr8040444
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effect of magnesium chloride as an additive of hydrothermal carbonization (HTC) of lignocellulosic biomass (Pinus radiata sawdust) was studied. The HTC tests were carried out at fixed conditions of temperature and residence time of 220 degrees C and 1 h, respectively, and varying the dose of magnesium chloride in the range 0.0-1.0 g MgCl2/g biomass. The carbonized product (hydrochar) was tested in order to determine its calorific value (HHV) while using PARR 6100 calorimeter, mass yield by gravimetry, elemental analysis using a LECO TruSpec elemental analyzer, volatile matter content, and ash content were obtained by standardized procedures using suitable ovens for it. The results show that using a dose of 0.75 g MgCl2/g biomass results in an impact on the mass yield that was almost equal to change operating conditions from 220 to 270 degrees C and from 0.5 to 1 h, without additive. Likewise, the calorific value increases by 33% for this additive dose, resulting in an energy yield of 68%, thus generating a solid fuel of prominent characteristics.
引用
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页数:12
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