Rhodium-Catalyzed Cyclization Reactions of Thiadiazoles with Phosphaalkynes to Prepare 1,3-Thiaphospholes

被引：18

作者：

Liang Wenbin ^{[1
]}

Nakajima, Kazunari ^{[2
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Syst Innovat, Bunkyo Ku, Tokyo 1138658, Japan

[2] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Tokyo 1138658, Japan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 25期

关键词：

Phosphaalkynes; Homogeneous catalysis; Cyclization; Thiaphospholes; Heterocycles; ORGANOPHOSPHORUS COMPOUNDS; CYCLOADDITION; REACTIVITY; COMPLEX; DIYNES;

D O I：

10.1002/ejoc.202000506

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new rhodium-catalyzed synthetic method is described for the preparation of 1,3-thiaphospholes. Cyclization reactions of various 1,2,3-thiadiazoles with phosphaalkynes in the presence of a rhodium precursor and a dcypp ligand afford the corresponding 1,3-thiaphospholes via denitrogenation of the 1,2,3-thiadiazoles.

引用

页码：3879 / 3882

页数：4

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