Modification and characterisation of terpolymer maleic anhydride-styrene-vinyl acetate by poly(ethylene adipate) copolymer

被引：2

作者：

Boztug, A. ^{[1
]}

机构：

[1] Cumhuriyet Univ, Fac Sci & Arts, Dept Chem, TR-58140 Sivas, Turkey

来源：

MATERIALS RESEARCH INNOVATIONS | 2007年 / 11卷 / 04期

关键词：

maleic anhydride; poly(ethylene adipate); modification; functional terpolymer; TMA;

D O I：

10.1179/143307507X246567

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In the present paper, poly(ethylene adipate) (PEA) copolymer of ethylene glycol/adipic acid was synthesised by the polycondensation in the status without an initiator at 180 degrees C for 5 h. It reacted with the PEA copolymer with maleic anhydride-styrene-vinyl acetate (MA-St-VA) terpolymer without using an initiator at 150 degrees C for 6 h. Thus, MA-St-VA terpolymer was modified by the ring opening method. The original MA-St-VA terpolymer and the modified terpolymer were characterised by Fourier transform infrared spectroscopy (FTIR), thermomechanical analysis (TMA) and the viscosimetric method. It was observed that the modified terpolymer was more elastic than the original terpolymer.

引用

页码：169 / 172

页数：4

共 26 条

[1] Compatibilizing effect of EPM-g-MA in EPDM/poly(trimethylene terephthalate) incompatible blends [J].

Aravind, I ;

Albert, P ;

Ranganathaiah, C ;

Kurian, JV ;

Thomas, S .

POLYMER, 2004, 45 (14) :4925-4937

[2] Viscoelastic properties of reactive and non-reactive blends of ethylene-methyl acrylate copolymers with styrene-maleic anhydride copolymer [J].

Bayram, G ;

Yilmazer, U ;

Xanthos, M .

POLYMER ENGINEERING AND SCIENCE, 2001, 41 (02) :262-274

[3] Reactively compatibilised polyamide6/ethylene-co-vinyl acetate blends: mechanical properties and morphology [J].

Bhattacharyya, AR ;

Ghosh, AK ;

Misra, A ;

Eichhorn, KJ .

POLYMER, 2005, 46 (05) :1661-1674

[4] Characterization and synthesis of maleic anhydride-styrene-vinyl acetate terpolymer ester derivatives [J].

Boztug, A ;

Basan, S .

JOURNAL OF MATERIALS SCIENCE, 2004, 39 (22) :6843-6846

[5] Preparation and thermomechanical characterization of poly(vinyl chloride) blends compatible with terpolymer-containing maleic anhydride [J].

Boztug, A .

JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (04) :1586-1589

[6] Thermomechanical and thermogravimetric analysis of blends of poly (vinyl chloride) (PVC) with maleic anhydride-allyl propionate copolymer [J].

Boztug, A ;

Zengin, HB ;

Basan, S .

JOURNAL OF MOLECULAR STRUCTURE, 2004, 697 (1-3) :61-64

[7] In situ compatibilization of polystyrene and polyurethane blends by using poly (styrene-co-maleic anhydride) as reactive compatibilizer [J].

Cassu, SN ;

Felisberti, MI .

JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 82 (10) :2514-2524

[8] MECHANISM OF ALTERNATING COPOLYMERIZATION OF VINYL-ACETATE AND MALEIC-ANHYDRIDE [J].

CAZE, C ;

LOUCHEUX, C .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1975, A 9 (01) :29-43

[9] On the compatibility of the IPP/PA6/EPDM blends with and without functionalized IPPI. Thermo-oxidative behaviour [J].

Darie, RN ;

Brebu, M ;

Vasile, C ;

Kozlowski, M .

POLYMER DEGRADATION AND STABILITY, 2003, 80 (03) :551-566

[10]

FELMING I, 1987, SPECTROSCOPIC METHOD, P35

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