Modification and characterisation of terpolymer maleic anhydride-styrene-vinyl acetate by poly(ethylene adipate) copolymer

被引:2
|
作者
Boztug, A. [1 ]
机构
[1] Cumhuriyet Univ, Fac Sci & Arts, Dept Chem, TR-58140 Sivas, Turkey
关键词
maleic anhydride; poly(ethylene adipate); modification; functional terpolymer; TMA;
D O I
10.1179/143307507X246567
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present paper, poly(ethylene adipate) (PEA) copolymer of ethylene glycol/adipic acid was synthesised by the polycondensation in the status without an initiator at 180 degrees C for 5 h. It reacted with the PEA copolymer with maleic anhydride-styrene-vinyl acetate (MA-St-VA) terpolymer without using an initiator at 150 degrees C for 6 h. Thus, MA-St-VA terpolymer was modified by the ring opening method. The original MA-St-VA terpolymer and the modified terpolymer were characterised by Fourier transform infrared spectroscopy (FTIR), thermomechanical analysis (TMA) and the viscosimetric method. It was observed that the modified terpolymer was more elastic than the original terpolymer.
引用
收藏
页码:169 / 172
页数:4
相关论文
共 35 条
  • [1] The modification and characterization of maleic anhydride-styrene-methyl metacrylate terpolymer by poly(ethylene adipate)
    Boztug, Ali
    Basan, Satilmis
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 830 (1-3) : 126 - 130
  • [2] Chemical modification and thermal characterisation of poly(allylpropionate-alt-maleic anhydride) copolymer modified by hexamethylenediamine
    Zengin, H. Bayram
    Boztug, A.
    Yilmaz, E.
    MATERIALS RESEARCH INNOVATIONS, 2008, 12 (02) : 90 - 93
  • [3] Additivation of the ethylene–vinyl acetate copolymer (EVA) with maleic anhydride (MA) and dicumyl peroxide (DCP): the impact of styrene monomer on cross-linking and functionalization
    Carlos Bruno Barreto Luna
    Eduardo da Silva Barbosa Ferreira
    Danilo Diniz Siqueira
    Edson Antonio dos Santos Filho
    Edcleide Maria Araújo
    Polymer Bulletin, 2022, 79 : 7323 - 7346
  • [4] Synthesis of poly(acrylic acid dodecyl ester-styrene-maleic anhydride) terpolymer and surface modification of glass fiber
    Wang, Jingchang
    Liu, Chunming
    Zhao, Qicheng
    Dong, Xu
    MATERIAL DESIGN, PROCESSING AND APPLICATIONS, PARTS 1-4, 2013, 690-693 : 1645 - 1648
  • [5] Synthesis of copolymer of maleic anhydride and vinyl acetate using antimony oxide as catalyst
    Pandey, A. K.
    Kumar, D.
    Pal, R. S.
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (05) : 4127 - 4128
  • [6] Modification of Maleic Anhydride-Styrene Copolymer with Noradrenaline by Chemical and Enzymatic Methods
    Karakus, Gulderen
    Yenidunya, Ali Fazil
    Zengin, Haci Bayram
    Polat, Zubeyde Akin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (04) : 2821 - 2828
  • [7] Modification and characterization of maleic anhydride-styrene-methyl metacrylate terpolymer using various alcohols
    Boztug, Ali
    Basan, Satilmis
    DESIGNED MONOMERS AND POLYMERS, 2006, 9 (06) : 617 - 626
  • [8] Additivation of the ethylene-vinyl acetate copolymer (EVA) with maleic anhydride (MA) and dicumyl peroxide (DCP): the impact of styrene monomer on cross-linking and functionalization
    Luna, Carlos Bruno Barreto
    da Silva Barbosa Ferreira, Eduardo
    Siqueira, Danilo Diniz
    dos Santos Filho, Edson Antonio
    Araujo, Edcleide Maria
    POLYMER BULLETIN, 2022, 79 (09) : 7323 - 7346
  • [9] Synthesis, characterization, microstructure determination and thermal studies of poly(N-vinyl-2-pyrrolidone-maleic anhydride-styrene) terpolymer
    Ajithkumar, Manayan Parambil
    Yashoda, Malgar Puttaiahgowda
    Prasannakumar, Shankarappa
    IRANIAN POLYMER JOURNAL, 2014, 23 (02) : 93 - 101
  • [10] Impact modification of polypropylene by ethylene propylene copolymer-grafted maleic anhydride
    Mehrabzadeh, M
    Nia, KH
    JOURNAL OF APPLIED POLYMER SCIENCE, 1999, 72 (10) : 1257 - 1265