Group 10 metal complexes of meso-aryl-substituted [26]hexaphyrins with a metal-carbon bond

被引：70
作者：
Mori, S
Shimizu, S
Taniguchi, R
Osuka, A [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto, Japan
[2] Japan Sci & Technol Agcy, Core Res Evolut Sci & Technol, Sakyo Ku, Kyoto 6068502, Japan
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 12期
关键词：
D O I：
10.1021/ic050447e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Nickel(II), palladium(II), and platinum(II) complexes of meso-aryl-substituted [26]hexaphyrin have been prepared and structurally characterized. In mono-metalated complexes, the metal ion is commonly bound with three pyrrolic nitrogen atoms and one pyrrolic beta-carbon, whereas a bis-Pd(II) complex exhibits a unique structure involving a Pd-C-alpha. bond. These results reveal novel coordination abilities of the hexaphyrin that lead to a metal-carbon bond at either pyrrolic C-beta or C-alpha position.
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收藏
页码：4127 / 4129
页数：3
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