Photophysics and photochemistry with Earth-abundant metals - fundamentals and concepts

被引：285

作者：

Foerster, Christoph ^{[1
]}

Heinze, Katja ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Dept Chem, Duesbergweg 10-14, D-55128 Mainz, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2020年 / 49卷 / 04期

关键词：

EXCITED-STATE; CU(I) COMPLEXES; EMISSION; DESIGN; PERSPECTIVE; DYNAMICS; CHROMIUM; PROGRESS; RUBY;

D O I：

10.1039/c9cs00573k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent exciting developments in the area of mononuclear photoactive complexes with Earth-abundant metal ions (Cu, Zr, Fe, Cr) for potential eco-friendly applications in (phosphorescent) organic light emitting diodes, in imaging and sensing systems, in dye-sensitized solar cells and as photocatalysts are presented. Challenges, in particular the extension of excited state lifetimes, and recent conceptual breakthroughs in substituting precious and rare-Earth metal ions (e.g. Ru, Ir, Pt, Au, Eu) in these applications by abundant ions are outlined with selected examples. Relevant fundamentals of photophysics and photochemistry are discussed first, followed by conceptual and instructive case studies.

引用

页码：1057 / 1070

页数：14

共 50 条

[1] The triplet excited state of ruthenium(II) bis(2,2:6′,2"-terpyridine):: Comparison between experiment and theory [J].

Amini, A ;

Harriman, A ;

Mayeux, A .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (06) :1157-1164

[2] The photophysics of photoredox catalysis: a roadmap for catalyst design [J].

Arias-Rotondo, Daniela M. ;

McCusker, James K. .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (21) :5803-5820

[3] The Legacy of Fossil Fuels [J].

Armaroli, Nicola ;

Balzani, Vincenzo .

CHEMISTRY-AN ASIAN JOURNAL, 2011, 6 (03) :768-784

[4]

Balzani V, 2007, TOP CURR CHEM, V280, P1, DOI 10.1007/978-3-540-73347-8

[5]

Balzani V., 2014, PHOTOCHEMISTRY PHOTO

[6]

Balzani V, 2007, TOP CURR CHEM, V281, pIX

[7] Photochemistry and photophysics of coordination compounds: Overview and general concepts [J].

Balzani, Vincenzo ;

Bergamini, Giacomo ;

Campagna, Sebastiano ;

Puntoriero, Fausto .

PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS I, 2007, 280 :1-36

[8] Biological Evaluation of the NIR-Emissive Ruby Analogue [Cr(ddpd)2][BF4]3 as a Photodynamic Therapy Photosensitizer [J].

Basu, Uttara ;

Otto, Sven ;

Heinze, Katja ;

Gasser, Gilles .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 1 (01) :37-41

[9] Sustainable metal complexes for organic light-emitting diodes (OLEDs) [J].

Bizzarri, Claudia ;

Spuling, Eduard ;

Knoll, Daniel M. ;

Volz, Daniel ;

Braese, Stefan .

COORDINATION CHEMISTRY REVIEWS, 2018, 373 :49-82

[10] A Tris(diisocyanide)chromium(0) Complex Is a Luminescent Analog of Fe(2,2′-Bipyridine)32+ [J].

Buldt, Laura A. ;

Guo, Xingwei ;

Vogel, Raphael ;

Prescimone, Alessandro ;

Wenger, Oliver S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (02) :985-992

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