Bottlebrush-shaped copolymers with cellulose diacetate backbone by a combination of ring opening polymerization and ATRP

被引：34

作者：

Vlcek, Petr ^{[1
]}

Janata, Miroslav ^{[1
]}

Latalova, Petra ^{[1
]}

Dybal, Jiri ^{[1
]}

Spirkova, Milena ^{[1
]}

Toman, Ludek ^{[1
]}

机构：

[1] Acad Sci Czech Republic, Inst Macromol Chem, CR-16206 Prague, Czech Republic

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 02期

关键词：

ATRP; bottlebrush copolymers; butyl acrylate; cellulose diacetate; epsilon-caprolactone; graft copolymers; methyl methacrylate; ring-opening polymerization; styrene;

D O I：

10.1002/pola.22406

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Graft copolymers with cellulose diacetate (CDA) backbone and both the poly(epsilon-caprolactone) and polystyrene, or poly(butyl acrylate) or PMMA grafts were prepared by two-step process. First, E-caprolactone (CL) was polymerized by ring-opening polymerization (ROP) initiated with CDA, partly funcionalized with 2-bromo-isobutyryl groups (degree of functionalization was 0.5). The p(CDA-g-CL) copolymers were used in the second step as polyfunctional macroinitiators of ATRP of the vinyl monomer, giving densely grafted copolymers with polyester and PSt, or PBuA, or PMMA grafts. The prepared copolymers were characterized by SEC, some of them also by FTIR spectroscopy and atomic force microscopy (AFM). (C) 2007 Wiley Periodicals, Inc.

引用

页码：564 / 573

页数：10

共 32 条

[1] RADICAL CHEMISTRY OF THIOHYDROXAMIC ACID-ESTERS [J].

BARTON, DHR ;

KRETZSCHMAR, G .

TETRAHEDRON LETTERS, 1983, 24 (52) :5889-5892

[2] Grafting: a versatile means to modify polymers - Techniques, factors and applications [J].

Bhattacharya, A ;

Misra, BN .

PROGRESS IN POLYMER SCIENCE, 2004, 29 (08) :767-814

[3]

Brandrup J., 1999, Polymer handbook, VII

[4] ATRP grafting from cellulose fibers to create block-copolymer grafts [J].

Carlmark, A ;

Malmström, EE .

BIOMACROMOLECULES, 2003, 4 (06) :1740-1745

[5] Atom transfer radical polymerization from cellulose fibers at ambient temperature [J].

Carlmark, A ;

Malmström, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) :900-901

[6] ROLE OF CERIC ION IN THE HETEROGENEOUS GRAFT-POLYMERIZATION OF OLEFINS ON CELLULOSE [J].

CASINOS, I .

POLYMER, 1992, 33 (06) :1304-1315

[7] Grafting studies onto cellulose by atom-transfer radical polymerization [J].

Coskun, M ;

Temüz, MM .

POLYMER INTERNATIONAL, 2005, 54 (02) :342-347

[8]

Daly WH, 2001, MACROMOL SYMP, V174, P155, DOI 10.1002/1521-3900(200109)174:1<155::AID-MASY155>3.0.CO

[9]

2-O

[10] Advances in cellulose ester performance and application [J].

Edgar, KJ ;

Buchanan, CM ;

Debenham, JS ;

Rundquist, PA ;

Seiler, BD ;

Shelton, MC ;

Tindall, D .

PROGRESS IN POLYMER SCIENCE, 2001, 26 (09) :1605-1688

← 1 2 3 4 →