Effect of external electric field on phase transitions of ferroelectric thin films

被引:6
作者
Lue Ye-Gang [1 ,2 ]
Liang Xiao-Lin [1 ]
Gong Yue-Qiu [2 ]
Zheng Xue-Jun [2 ]
Liu Zhi-Zhuang [1 ]
机构
[1] Hunan Univ Sci & Engn, Yongzhou 425100, Peoples R China
[2] Xiangtan Univ, Fac Mat & Photoelect Phys, Xiangtan 411105, Peoples R China
关键词
ferroelectric thin film; phase transition; scanning probe microscopy; misfit strain; DOMAIN;
D O I
10.7498/aps.59.8167
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A nonlinear thermodynamic theory is used to investigate the effect of external electric field on the phase transitions of Pb(Zr0.3Ti0.7) O-3 (PZT) thin films epitaxially grown on dissimilar cubic substrates. The "misfit strain-external electric filed" phase diagram and the relationship between electirc filed and polarization are constructed for PZT thin films. The external electric field can transform the monoclinic r phase into the c phase, when its value reaches 186 kV/cm for PZT thin film grown on the SrTiO3 substrate. On the other hand, the domain switching of PZT thin film is investigated experimentally by scanning probe microscopy (SPM) via varying the applied polarizing electric field. The piezo-phase images reveal that most ferroelectric domains are clearly detectable. In the r phase, the domains can be reversed into the direction of polarization of the c phase, when the applied electric field increases to 200 kV/cm, which is close to the theoretical value (186 kV/cm).
引用
收藏
页码:8167 / 8171
页数:5
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