Palladium-catalysed hydroamidocarbonylation of 1,3-dienes

被引：24

作者：

Li, Haoquan ^{[1
]}

Fang, Xianjie ^{[1
]}

Jackstell, Ralf ^{[1
]}

Neumann, Helfried ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse EV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 44期

关键词：

SELECTIVE HYDROFORMYLATION; CARBONYLATION REACTIONS; EFFICIENT SYNTHESIS; ALIPHATIC-AMINES; METAL COMPLEXES; LIGANDS; ACID; AMINOCARBONYLATION; ALKENES; OLEFINS;

D O I：

10.1039/c6cc03017c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report our recent result on the development of the selective catalytic method towards the synthesis of beta,gamma-unsaturated imides via Pd-catalysed hydroamidocarbonylation of conjugated dienes. Note that this reaction proceeds under acid additive free conditions. Various dienes, including those of high industrial value (e.g. isoprene, 1,3-butadiene), are shown to be compatible with our established method (28 examples, 40-99% yield), which leads to the corresponding beta,gamma-unsaturated imides in a highly efficient and atom-economic fashion.

引用

页码：7142 / 7145

页数：4

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