Hollow and filled rectangular parallelopiped carbon nanocapsules catalyzed by calcium and strontium

被引:4
作者
Saito, Y [1 ]
Matsumoto, T [1 ]
机构
[1] Mie Univ, Dept Elect & Elect Engn, Tsu, Mie 514, Japan
关键词
nanoparticle; carbon nanocapsule; graphite; calcium; strontium;
D O I
10.1016/S0022-0248(98)00013-X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A new form of graphitic cages in nanometer scale, rectangular parallelopiped (or cube), was produced by are evaporation of a carbon electrode containing calcium or strontium. Both the empty and the filled rectangular nanocapsules averaging 20-100 nm in size were formed, though the empty ones were dominant. The rectangular cages were made up of multi-walled (5-20 layers) graphitic carbon. The encapsulated materials were beta-CaC2(tetragonal), gamma-CaC2(cubic) and delta-CaC2 (monoclinic) for C/Ca evaporation, and beta-SrC2 (tetragonal) and metallic Sr for C/S revaporation. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:402 / 409
页数:8
相关论文
共 26 条
  • [11] CARBON NANOCAPSULES GROWN ON CARBON-FIBERS
    KUSUNOKI, M
    IKUHARA, Y
    KON, J
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1995, 34 (03): : 1610 - 1614
  • [12] Massalski T. B., 1990, BINARY ALLOY PHASE D, V1
  • [13] SINGLE-CRYSTAL METALS ENCAPSULATED IN CARBON NANOPARTICLES
    RUOFF, RS
    LORENTS, DC
    CHAN, B
    MALHOTRA, R
    SUBRAMONEY, S
    [J]. SCIENCE, 1993, 259 (5093) : 346 - 348
  • [14] Synthesis, crystal structures and magnetic properties of Co particles encapsulated in carbon nanocapsules
    Saito, Y
    Ma, J
    Nakashima, J
    Masuda, M
    [J]. ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1997, 40 (1-4): : 170 - 172
  • [15] IRON PARTICLES NESTING IN CARBON CAGES GROWN BY ARC-DISCHARGE
    SAITO, Y
    YOSHIKAWA, T
    OKUDA, M
    FUJIMOTO, N
    YAMAMURO, S
    WAKOH, K
    SUMIYAMA, K
    SUZUKI, K
    KASUYA, A
    NISHINA, Y
    [J]. CHEMICAL PHYSICS LETTERS, 1993, 212 (3-4) : 379 - 383
  • [16] CORRELATION BETWEEN VOLATILITY OF RARE-EARTH-METALS AND ENCAPSULATION OF THEIR CARBIDES IN CARBON NANOCAPSULES
    SAITO, Y
    OKUDA, M
    YOSHIKAWA, T
    KASUYA, A
    NISHINA, Y
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (27) : 6696 - 6698
  • [17] GROWTH AND STRUCTURE OF GRAPHITIC TUBULES AND POLYHEDRAL PARTICLES IN ARC-DISCHARGE
    SAITO, Y
    YOSHIKAWA, T
    INAGAKI, M
    TOMITA, M
    HAYASHI, T
    [J]. CHEMICAL PHYSICS LETTERS, 1993, 204 (3-4) : 277 - 282
  • [18] CARBON NANOCAPSULES ENCAGING METALS AND CARBIDES
    SAITO, Y
    YOSHIKAWA, T
    OKUDA, M
    FUJIMOTO, N
    SUMIYAMA, K
    SUZUKI, K
    KASUYA, A
    NISHINA, Y
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1993, 54 (12) : 1849 - 1860
  • [19] Encapsulation of carbides of chromium, molybdenum and tungsten in carbon nanocapsules by arc discharge
    Saito, Y
    Matsumoto, T
    Nishikubo, K
    [J]. JOURNAL OF CRYSTAL GROWTH, 1997, 172 (1-2) : 163 - 170
  • [20] NANOPARTICLES AND FILLED NANOCAPSULES
    SAITO, Y
    [J]. CARBON, 1995, 33 (07) : 979 - 988